{"id":6,"date":"2015-07-23T14:07:24","date_gmt":"2015-07-23T14:07:24","guid":{"rendered":"https:\/\/my.vanderbilt.edu\/schley\/publications\/"},"modified":"2025-07-10T21:37:50","modified_gmt":"2025-07-11T02:37:50","slug":"publications","status":"publish","type":"page","link":"https:\/\/my.vanderbilt.edu\/schley\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"

Categories<\/h4>\n

Work from our Group<\/a>
\nBook Chapters and Perspectives<\/a>
\nCollaborative Publications<\/a>
\nPrior to Vanderbilt<\/a><\/p>\n

\n

Work from our Group<\/h4>\n
    \n
  1. Tandem Oligomerization-Hydrogenation Using Br\u00f8nsted Acidic Iridium Hydride Catalysts<\/strong><\/li>\n

    Leitgeb, A. J.; Chapp, S. M.; Fast, C. D.; Fink, K. E.; Schley, N. D.
    \nOrganometallics<\/em>, 2025.
    \nDOI:     10.1021\/acs.organomet.5c00160<\/a>
    \n\"\"<\/p>\n

    \"orlef7.2024.26.issue-29.largecover\"<\/a><\/p>\n

  2. Bis(bicyclo[1.1.1]pentyl)chlorophosphine as a Precursor for the Preparation of Bis(bicyclo[1.1.1]pentyl)phosphines<\/strong><\/li>\n

    Perry, G. L.; Schley, N. D.
    \nOrg. Lett.<\/em>, 2024, 26, 29, 6071-6075.
    \nDOI:     10.1021\/acs.orglett.4c01190<\/a>
    \n\"chlorophos\"<\/p>\n

  3. Tris(bicyclo[1.1.1]pentyl)phosphine: An Exceptionally Small Tri-tert<\/strong><\/em>-alkylphosphine and Its Bis-Ligated Pd(0) Complex<\/strong><\/li>\n

    Perry, G. L.; Schley, N. D.
    \nJ. Am. Chem. Soc.<\/em>, 2023, 145, 7005\u20137010.
    \nDOI:     10.1021\/jacs.3c00885<\/a>
    \nHighlighted: Org. Process Res. Dev.<\/em> 2023, 27, 6, 993\u20131002. DOI:     10.1021\/acs.oprd.3c00176<\/a>
    \n\"bcp\"<\/p>\n

  4. Light-Promoted Transfer of an Iridium Hydride in Alkyl Ether Cleavage<\/strong><\/li>\n

    Fast, C. D.; Schley, N. D.
    \nOrganometallics<\/em>, 2021, 40, 3291\u20133297.
    \nDOI:     10.1021\/acs.organomet.1c00391<\/a>
    \n\"photohydr\"<\/p>\n

  5. Selective demethylation of O-aryl glycosides by iridium-catalyzed hydrosilylation <\/strong><\/li>\n

    Jones, C. A. H.; Schley, N. D.
    \nChem. Commun.<\/em>, 2021, 57, 5953\u20135956.
    \nDOI:     10.1039\/D1CC00496D<\/a>
    \n\"carb_dem\"<\/p>\n

  6. Reversible C(sp3<\/sup>)-Si Oxidative Addition of Unsupported Organosilanes: Effects of Silicon Substituents on Kinetics and Thermodynamics<\/strong><\/li>\n

    Chapp, S. M.; Schley, N. D.
    \nJ. Am. Chem. Soc.<\/em>, 2021, 143, 5534\u20135539.
    \nDOI:     10.1021\/jacs.1c01564<\/a>
    \n\"silyl\"<\/p>\n

  7. Ligand-Driven Advances in Iridium-Catalyzed sp3<\/sup> C\u2013H Borylation: 2,2\u2032-Dipyridylarylmethane<\/strong><\/li>\n

    Jones, M. R.; Schley, N. D.
    \nSynlett<\/em>, 2021, 32, 845-850.
    \nDOI:     10.1055\/a-1344-1904<\/a>
    \n\"synpac\"<\/p>\n

  8. Product Inhibition in Nucleophilic Aromatic Substitution through DPPPent-Supported \u03c0-Arene Catalysis<\/strong><\/li>\n

    Mueller, B. R. J.; Schley, N. D.
    \nDalton Transactions<\/em>, 2020, 49, 10114\u201310119.
    \nDOI:     10.1039\/D0DT00786B<\/a>
    \n\"arene\"<\/p>\n

  9. Selectivity and Mechanism of Iridium-Catalyzed Cyclohexyl Methyl Ether Cleavage<\/strong><\/li>\n

    Fast, C. D.; Jones, C. A. H.; Schley, N. D.
    \nACS Catalysis<\/em>, 2020, 10, 11, 6450\u20136456.
    \nDOI:     10.1021\/acscatal.0c01718<\/a>
    \nFeatured at Organic-chemistry.org:     Highlights: Reduction<\/a>
    \n\"demeth\"<\/p>\n

  10. Group-Transfer Reactions of a Cationic Iridium Alkoxycarbene Generated by Ether Dehydrogenation<\/strong><\/li>\n

    Chapp, S. M.; Schley, N. D.
    \nInorg. Chem.<\/em>, 2020, 59, 10, 7143\u20137149.
    \nDOI:     10.1021\/acs.inorgchem.0c00609<\/a>
    \n\"grptransf\"<\/p>\n

  11. Iridium-Catalyzed sp3<\/sup> C\u2013H Borylation in Hydrocarbon Solvent Enabled by 2,2\u2032-Dipyridylarylmethane Ligands<\/strong><\/li>\n

    Jones, M. R.; Fast, C. D.; Schley, N. D.
    \nJ. Am. Chem. Soc.<\/em>, 2020, 142, 14, 6488-6492.
    \nDOI:     10.1021\/jacs.0c00524<\/a>
    \nFeatured at Organic-chemistry.org:     Highlights: C-H functionalization<\/a>
    \n\"jonesboryl\"<\/p>\n

  12. Selective alkyl ether cleavage by cationic bis(phosphine)iridium complexes<\/strong><\/li>\n

    Jones, C. A. H.; Schley, N. D.
    \nOrg. Biomol. Chem.,<\/em> 2019. 17, 1744-1748.
    \nDOI:     10.1039\/C8OB02298D<\/a>
    \nInvited submission – New Talent, 2019.<\/em>
    \n\"debenzy\"<\/p>\n

  13. Formation of a Delocalized Iridium Benzylidene with Azaquinone Methide Character via Alkoxycarbene Cleavage<\/strong><\/li>\n

    Zhang, Y.; Mueller, B. R. J.; Schley, N. D.
    \nOrganometallics<\/em>, 2018, 37 (12), pp 1825\u20131828.
    \nDOI:     10.1021\/acs.organomet.8b00249<\/a>
    \n\"azaqu\"<\/p>\n

  14. Evidence for reversible cyclometalation in alkane dehydrogenation and C-O bond cleavage at iridium bis(phosphine) complexes<\/strong><\/li>\n

    Chapp, S. M.; Schley, N. D.
    \nOrganometallics<\/em>, 2017, 36 (22), pp 4355\u20134358.
    \nDOI:     10.1021\/acs.organomet.7b00676<\/a>
    \n\"irallyl\"<\/p>\n

  15. Reversible alkoxycarbene formation by C\u2013H activation of ethers via discrete, isolable intermediates<\/strong><\/li>\n

    Zhang, Y.; Schley, N. D.
    \nChem. Commun.<\/em>, 2017, 53, 2130\u20132133.
    \nDOI:     10.1039\/C6CC09838J<\/a>
    \n\"dicarbene\"<\/p>\n

    \n

    Book Chapters and Perspectives<\/h4>\n
  16. (1,5-Cyclooctadiene)bis(2-Me-allyl)ruthenium(II)<\/strong><\/li>\n

    Li, H.; Colacot, T. J; Schley, N. D.
    \nEncyclopedia of Reagents for Organic Synthesis<\/em>, 2021.
    \nDOI:     10.1002\/047084289X.rn01145.pub2<\/a><\/p>\n

  17. Pioneers and Influencers in Organometallic Chemistry: Professor Robert Crabtree\u2019s Storied Career via an Unusual Journey to the Ivy League<\/strong><\/li>\n

    Dobereiner, G. E.; Hazari, N.; Schley, N. D.
    \nOrganometallics<\/em> 2021, 40, 295\u2013301.
    \nDOI:     10.1021\/acs.organomet.0c00797<\/a><\/p>\n

    \n

    Collaborative Work<\/h4>\n
  18. Unlocking Chromium Decarboxylative Ligand-to-Metal Charge Transfer: Efficient and Redox-Neutral Allylation of Aldehydes Using Carboxylic Acids<\/strong><\/li>\n

    Wu, S.\u2020; Jiao, Z.\u2020; Sung, A. T.; Faulhaber, A. B.; Schley, N. D.; Schuppe, A. W.
    \nJ. Am. Chem. Soc.<\/em> 2025, 147, 26, 22759\u201322767.
    \nDOI:     10.1021\/jacs.5c04691<\/a>
    \n\"\"<\/p>\n

  19. Photocatalyzed Epimerization of Quaternary Stereocenters<\/strong><\/li>\n

    Wu, L.; McIntyre, B. N.; Wu, S.; Jiao, Z.; Fox, C. B.; Schley, N. D.; Schuppe, A. W.
    \nJ. Am. Chem. Soc.<\/em> 2025, 147, 13, 11080\u201311088.
    \nDOI:     10.1021\/jacs.4c16769<\/a>
    \n\"\"<\/p>\n

  20. Total Synthesis and Pharmacological Evaluation of Phochrodines A\u2013C<\/strong><\/li>\n

    Bouchard, J. L.; Chang, S.; Krishnan, S.; Presley, C. C.; Boutaud, O.; Schley, N. D.; Engers, D. W.; Engers, J. L.; Lindsley, C. W.; Bender, A. M.;
    \nJ. Nat. Prod.<\/em> 2025, 88, 4, 996\u20131003.
    \nDOI:     10.1021\/acs.jnatprod.5c00104<\/a>
    \n\"\"<\/p>\n

  21. Synthesis, Structure, and Reactivity of Copper(I) Proazaphosphatrane Complexes<\/strong><\/li>\n

    Hoskins-Harris, J. E.; Kotera, K.; Hoilette, D. A., Jr.; Apostolou, W. E.; Osenga, V. A.; Thomas, J. I.; Schley, N. D.; Donald, K. J.; Johnson, M. W.
    \nInorg. Chem.<\/em> 2025, 64, 1132-1138.
    \nDOI:     10.1021\/acs.inorgchem.4c04779<\/a>
    \n\"\"<\/p>\n

  22. Diastereoselective dearomative cycloaddition of bicyclobutanes with pyridinium ylides: a modular approach to multisubstituted azabicyclo[3.1.1]heptanes<\/strong><\/li>\n

    Dhake, K.; Woelk, K. J.; Krueckl, L. D. N.; Alberts, F.; Mutter, J.; Pohl, M. O.; Thomas, G. T.; Sharma, M.; Bjornerud-Brown, J.; Fern\u00e1ndez, N. P.; Schley, N. D.; Leitch, D. C.
    \nChem. Commun.<\/em> 2024, 60, 13008-13011.
    \nDOI:     10.1039\/D4CC04730C<\/a>
    \n\"\"<\/p>\n

  23. Mechanisms and Site Selectivity of (Het)Ar\u2013X Oxidative Addition to Pd(0) Are Controlled by Frontier Molecular Orbital Symmetry<\/strong><\/li>\n

    Lu, J.; Schley, N. D.; Paci, I.; Leitch, D. C.
    \nOrganometallics<\/em> 2024, 43, 24, 3192\u20133203.
    \nDOI:     10.1021\/acs.organomet.4c00224<\/a>
    \n\"images_large_om4c00224_0013\"<\/p>\n

  24. A Thermally Stable, Alkene-Free Palladium Source for Oxidative Addition Complex Formation and High-Turnover Catalysis<\/strong><\/li>\n

    Huang, J.; Ho, D. B.; Gaube, G.; Celuszak, H.; Becica, J.; Thomas, G. T.; Schley, N. D.; Leitch, D. C.
    \nOrganometallics<\/em> 2024, 43, 20, 2403\u20132412.
    \nDOI:     10.1021\/acs.organomet.4c00125<\/a>
    \n\"images_large_om4c00125_0009\"<\/p>\n

  25. Alkene-Coordinated Palladium(0) Cross-Coupling Precatalysts: Comparing Oxidative Addition and Catalytic Reactivity for Dimethyl Fumarate and Maleic Anhydride Stabilizing Ligands<\/strong><\/li>\n

    Thomas, G. T.; Litman, J. Z.; Ho, D. B.; Huang, J.; Blonska, K.; Schley, N. D.; Leitch, D. C.
    \nOrganometallics<\/em> 2024, 43, 20, 2413\u20132426.
    \nDOI:     10.1021\/acs.organomet.4c00065<\/a>
    \n\"images_large_om4c00065_0017\"<\/p>\n

  26. Five Hypotheses on the Origins of Temperature Dependence of 77Se NMR Shifts in Diselenides<\/strong><\/li>\n

    Koziel, A. C.; Bortoli, M.; Tremblay, M.; Zhao, Y.; Orian, L.; Yang, Z. J.; Schley, N. D.; Macdonald, J. E.,
    \nInorg. Chem.<\/em> 2024, 63, 12063-12072.
    \nDOI:     10.1021\/acs.inorgchem.4c01025<\/a>
    \n\"images_large_ic4c01025_0009\"<\/p>\n

  27. Rapid sp3<\/sup>-Enriched Scaffold Generation via a Selective Aziridine Amide Ring-Opening Reaction<\/strong><\/li>\n

    Masahito, A.; Coleman, J. S.; Presley, C. C.; Schley, N. D.; Lindsley, C. W.
    \nJ. Org. Chem.<\/em> 2024, 89, 5, 3500-3508.
    \nDOI:     10.1021\/acs.joc.3c02952<\/a>
    \n\"images_large_jo3c02952_0008\"<\/p>\n

  28. Comparative Analysis of the Donor Properties of Isomeric Pyrrolyl Phosphine Ligands<\/strong><\/li>\n

    Osenga, V. A.; Sykes, N. C.; Pa, S.; Bambha, M. K.; Schley, N. D.; Johnson, M. W.
    \nOrganometallics<\/em> 2024, 43, 14-20.
    \nDOI:     10.1021\/acs.organomet.3c00467<\/a>
    \n\"images_large_om3c00467_0014\"<\/p>\n

  29. Enolate addition to bicyclobutanes enables expedient access to 2-oxo-bicyclohexane scaffolds<\/strong><\/li>\n

    Woelk, K. J.; Dhake, K.; Schley, N. D.; Leitch, D. C.
    \nChem. Commun.<\/em> 2023, 59, 13847-13850.
    \nDOI:     10.1039\/D3CC04234K<\/a>
    \n\"Get\"<\/p>\n

  30. Vanol-Supported Lanthanide Complexes for Strong Circularly Polarized Luminescence at 1550 nm<\/strong><\/li>\n

    Adewuyi, J. A.; Schley, N. D.; Ung, G.
    \nChem. Eur. J.<\/em> 2023, 29, e202300800.
    \nDOI:     10.1002\/chem.202300800<\/a>
    \n\"chem202300800-toc-0001-m\"<\/p>\n

  31. Synthesis, characterization and absolute configurations of methyl ladderanoates<\/strong><\/li>\n

    Harris, C. M.; Harris, T. M.; Stec, D. F.; Schley, N. D.; Johnson, J. L.; Covington, C. L.; Polavarapu, P. L.
    \nChirality<\/em> 2023, 35, 49-57.
    \nDOI:     10.1002\/chir.23515<\/a>
    \n\"chir23515-toc-0001-m\"<\/p>\n

  32. Spinolate Lanthanide Complexes for High Circularly Polarized Luminescence Metrics in the Visible and Near-Infrared<\/strong><\/li>\n

    Willis, B.-A. N.; Schnable, D.; Schley, N. D.; Ung, G.
    \nJ. Am. Chem. Soc.<\/em> 2022, 144, 22421-22425.
    \nDOI:     10.1021\/jacs.2c10364<\/a>
    \n\"images_large_ja2c10364_0006\"<\/p>\n

  33. Reassessment of N2<\/sub> activation by low-valent Ti-amide complexes: a remarkable side-on bridged bis-N2<\/sub> adduct is actually an arene adduct<\/strong><\/li>\n

    Huh, D. N.; Koby, R, F.; Stuart, Z. E.; Dunscomb, R. J.; Schley, N. D.; Tonks, I. A.
    \nChem. Sci.<\/em> 2022, 13, 13330-13337.
    \nDOI:     10.1039\/D2SC04368H<\/a>
    \n\"7c16e5f17bae5f9741ee6cc10dd05d32c70ec043\"<\/p>\n

  34. Structure\u2013Activity Relationships for the N<\/strong><\/em>-Me- Versus N<\/strong><\/em>-H-Amide Modification to Macrocyclic ent<\/strong><\/em>-Verticilide Antiarrhythmics<\/strong><\/li>\n

    Smith, A. N.; Thorpe, M. P.; Blackwell, D. J.; Batiste, S. M.; Hopkins, C. R.; Schley, N. D.; Knollmann, B. C.; Johnston, J. N.
    \nACS Med. Chem. Lett. <\/em> 2022, 13, 1755-1762.
    \nDOI:     10.1021\/acsmedchemlett.2c00377<\/a>
    \n\"images_large_ml2c00377_0011\"<\/p>\n

  35. Circularly Polarized Luminescence from Uranyl Improves Resolution of Electronic Transitions<\/strong><\/li>\n

    Schnable, D.; Schley, N. D.; Ung, G.
    \nJ. Am. Chem. Soc.<\/em> 2022, 144, 10718-10722.
    \nDOI:     10.1021\/jacs.2c03791<\/a>
    \n\"images_large_ja2c03791_0006\"<\/p>\n

  36. Strong Circularly Polarized Luminescence at 1550 nm from Enantiopure Molecular Erbium Complexes<\/strong><\/li>\n

    Mukthar, N. F. M.; Schley, N. D.; Ung, G.
    \nJ. Am. Chem. Soc.<\/em> 2022, 144, 6148-6153.
    \nDOI:     10.1021\/jacs.2c01134<\/a>
    \n\"images_large_ja2c01134_0007\"<\/p>\n

  37. Synthesis of bright water-soluble circularly polarized luminescence emitters as potential sensors<\/strong><\/li>\n

    Adewuyi, J. A.; Schley, N. D.; Ung, G.
    \nInorganic Chemistry Frontiers<\/em> 2022, 9, 1474-1480.
    \nDOI:     10.1039\/D1QI01398J<\/a>
    \n\"D1QI01398J\"<\/p>\n

  38. Trace Oxygen Affects Osmium Redox Polymer Synthesis for Wired Enzymatic Biosensors<\/strong><\/li>\n

    Calhoun, M. C.; Stachurski, C. D.; Winn, S. L.; Gizzie, E.; Daniel, A. W.; Schley, N. D.; Cliffel, D. E.
    \nJ. Electrochem. Soc.<\/em> 2022, 169, 016506.
    \nDOI:     10.1149\/1945-7111\/ac42a0<\/a><\/p>\n

  39. Fluorine-induced diastereodivergence discovered in an equally rare enantioselective syn-aza-Henry reaction<\/strong><\/li>\n

    Bing, J. A.; Schley, N. D.; Johnston, J. N.
    \nChemical Science<\/em> 2022, 13, 2614-2623.
    \nDOI:     10.1039\/D1SC05910F<\/a>
    \n\"fdfcbb564a8f93bf18cd3122cbb6d125f04478c3\"<\/p>\n

  40. Substituent Effect on the Circularly Polarized Luminescence of C1-Symmetric Carbene-Copper(I) Complexes<\/strong><\/li>\n

    Braker, E. E.; Mukthar, N. F. M.; Schley, N. D.; Ung, G.
    \nChemPhotoChem<\/em> 2021, 5, 902-905.
    \nDOI:     10.1002\/cptc.202100068<\/a>
    \n\"cptc202100068-toc-0001-m\"<\/p>\n

  41. Synthesis and Cytotoxic Evaluation of Arimetamycin A and Its Daunorubicin and Doxorubicin Hybrids<\/strong><\/li>\n

    Huseman, E. D.; Byl, J. A. W.; Chapp, S. M.; Schley, N. D.; Osheroff, N.; Townsend, S. D.
    \nACS Central Science<\/em> 2021, 7, 1327-1337.
    \nDOI:     10.1021\/acscentsci.1c00040<\/a>
    \n\"images_large_oc1c00040_0010\"<\/p>\n

  42. Electronic structure analysis and reactivity of the bimetallic bis-titanocene vinylcarboxylate complex, [(Cp2<\/sub>Ti)2<\/sub>(O2<\/sub>C3<\/sub>TMS2<\/sub>)].<\/strong><\/li>\n

    Huh, D. N.; Maity, A.; Van Trieste, G. P.; Schley, N. D.; Powers, D. C.; Tonks, I. A.
    \nPolyhedron<\/em> 2021, 207, 115368.
    \nDOI:     10.1016\/j.poly.2021.115368<\/a>
    \n\"1-s2.0-S0277538721003508-ga1\"<\/p>\n

  43. Di(indenyl)beryllium<\/strong><\/li>\n

    Koby, R. F.; Schley, N. D.; Hanusa, T. P.
    \nAngew. Chem. Int. Ed.<\/em> 2021, 60, 21174-21178.
    \nDOI:     10.1002\/anie.202107980<\/a>
    \n\"anie202107980-toc-0001-m\"<\/p>\n

  44. Mechanochemical Formation, Solution Rearrangements, and Catalytic Behavior of a Polymorphic Ca\/K Allyl Complex<\/strong><\/li>\n

    Koby, R. F.; Doerr, A. M.; Rightmire, N. R.; Schley, N. D.; Brennessel, W. W.; Long, B. K.; Hanusa, T. P.
    \nChem. Eur. J.<\/em> 2021, 27,8195-8202.
    \nDOI:     10.1002\/chem.202100589<\/a>
    \n\"chem202100589-toc-0001-m\"<\/p>\n

  45. How important are the intermolecular hydrogen bonding interactions in methanol solvent for interpreting the chiroptical properties?<\/strong><\/li>\n

    Polavarapu, P. L.; Santoro, E.; Covington, C. L.; Johnson, J. L.; Puente, A. R.; Schley, N. D.; Kallingathodi, Z.; Prakasan, P. C.; Haleema, S.; Thomas, A. A.; Ibnusaud, I.
    \nSpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy<\/em> 2021, 247, 119094
    \nDOI:     10.1016\/j.saa.2020.119094<\/a>
    \n\"1-s2.0-S1386142520310738-ga1\"<\/p>\n

  46. High circularly polarized luminescence brightness from analogues of Shibasaki’s lanthanide complexes.<\/strong><\/li>\n

    Deng, M.; Schley, N. D.; Ung, G.
    \nChem. Commun<\/em>. 2020, 56, 14813-14816
    \nDOI:     10.1039\/D0CC06568D<\/a>
    \n\"shibisaki\"<\/p>\n

  47. Alkali-metal- and halide-free dinuclear mixed-valent samarium and europium complexes.<\/strong><\/li>\n

    Mukthar, N. F. M.; Schley, N. D.; Ung, G.
    \nDalton Transactions<\/em> 2020, 49, 16059-16061
    \nDOI:     10.1039\/D0DT01095B<\/a>
    \n\"europ\"<\/p>\n

  48. Systematic evaluation of the electronic effect of aluminum-containing ligands in iridium\u2013aluminum and rhodium\u2013aluminum bimetallic complexes<\/strong><\/li>\n

    Charles, R. M.; Taylor, N. S.; Mercado, A. A.; Frost, C. E.; Yokley, T. W.; Eckenhoff, W. T.; Schley, N. D.; DeYonker, N. J.; Brewster, T. P.
    \nDalton Transactions<\/em> 2020, 49, 13029-13043
    \nDOI:     10.1039\/D0DT02472D<\/a>
    \n\"bimet\"<\/p>\n

  49. CO2<\/sub> Capture by 2-(Methylamino)pyridine Ligated Aluminum Alkyl Complexes.<\/strong><\/li>\n

    Yokley, T. W.; Tupkar, H.; Schley, N. D.; DeYonker, N. J.; Brewster, T. P.
    \nEur. J. Inorg. Chem.<\/em> 2020, 2020, 2958-2967.
    \nDOI:     10.1002\/ejic.202000437<\/a>
    \n\"alum\"<\/p>\n

  50. Study and modular synthesis of unsymmetrical bis(phosphino)pyrrole ligands.<\/strong><\/li>\n

    Fokwa, H. D.; Vidlak, J. F.; Weinberg, S. C.; Duplessis, I. D.; Schley, N. D.; Johnson, M. W.
    \nDalton Transactions<\/em> 2020, 49, 9957-9960.
    \nDOI:     10.1039\/D0DT02063J<\/a>
    \n\"pyrolyl\"<\/p>\n

  51. Circularly Polarized Luminescence from Enantiopure C2<\/sub>-Symmetrical Tetrakis(2-pyridylmethyl)-1,2-diaminocyclohexane Lanthanide Complexes.<\/strong><\/li>\n

    Ayers, K. M.; Schley, N. D.; Ung, G.
    \nInorg. Chem.<\/em> 2020, 59, 11, 7657\u20137665.
    \nDOI:     10.1021\/acs.inorgchem.0c00628<\/a>
    \n\"images_large_ic0c00628_0010\"<\/p>\n

  52. Synthesis of Enantiopure Lanthanide Complexes Supported by Hexadentate N,N\u2032-Bis(methylbipyridyl)bipyrrolidine and Their Circularly Polarized Luminescence.<\/strong><\/li>\n

    Schnable, D.; Freedman, K.; Ayers, K. M.; Schley, N. D.; Kol, M.; Ung, G.
    \nInorg. Chem.<\/em> 2020, 59, 8498-8504.
    \nDOI:     10.1021\/acs.inorgchem.0c00946<\/a>
    \n\"images_large_ic0c00946_0005\"<\/p>\n

  53. Algal Toxin Goniodomin A Binds Potassium Ion Selectively Yielding a Conformationally Altered Complex Having Biological Consequences.<\/strong><\/li>\n

    Tainter, C. J.; Schley, N. D.; Harris, C. M.; Stec, D. F.; Song, A. K.; Balinski, A.; May, J. C.; McLean, J. A.; Reece, K. S.; Harris, T. M.,
    \nJournal of Natural Products<\/em>, 2020, 83, 4, 1069\u20131081.
    \nDOI:     10.1021\/acs.jnatprod.9b01094<\/a>
    \n\"images_large_np9b01094_0008\"<\/p>\n

  54. Synthesis and Electronic Characterization of Iridium-Aluminum and Rhodium-Aluminum Heterobimetallic Complexes Bridged by 3-Oxypyridine and 4-Oxypyridine.<\/strong><\/li>\n

    Charles III, R. M.; Tupkar, H.; Helland, S. D.; Mercado, A. A.; Eckenhoff, W. T.; Schley, N. D.; DeYonker, N. J.; Brewster, T. P.
    \nEur. J. Inorg. Chem. <\/em>2020, 2020, 1192-1198.
    \nDOI:     10.1002\/ejic.201901317<\/a>
    \n\"ejic201901317-toc-0001-m\"<\/p>\n

  55. An \u03b73<\/sup><\/em>-Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg\/K Allyl Complex.<\/strong><\/li>\n

    Koby, R. F.; Doerr, A. M.; Rightmire, N. R.; Schley, N. D.; Long, B. K.; Hanusa, T. P.
    \nAngew. Chem. Int. Ed. <\/em>2020, 59, 9542-9548.
    \nDOI:     10.1002\/anie.201916410<\/a>
    \n\"anie201916410-toc-0001-m\"<\/p>\n

  56. Rhodium and iridium NNO-Scorpionate complexes: synthesis, structure, and reactivity with aluminum alkyls.<\/strong><\/li>\n

    Yokley, T. W.; Schley, N. D.; Brewster, T. P.
    \nInorg. Chim. Acta 2020, 506, 119529.<\/em>
    \nDOI:     10.1016\/j.ica.2020.119529<\/a>
    \n\"1-s2.0-S0020169319315178-ga1\"<\/p>\n

  57. Yellow Circularly Polarized Luminescence from C1<\/sub>\u2010Symmetrical Copper(I) Complexes<\/strong><\/li>\n

    Deng, M.; Mukthar, N. F. M.; Schley, N. D.; Ung, G.
    \nAngew. Chem. Int. Ed.<\/em>, 2020, 59,1228\u20131231.
    \nDOI:     10.1002\/anie.201913672<\/a>
    \n\"anie201913672-toc-0001-m\"<\/p>\n

  58. Catalytic, Enantioselective Synthesis of Cyclic Carbamates from Dialkyl Amines by CO2<\/sub>-Capture: Discovery, Development, and Mechanism<\/strong><\/li>\n

    Yousefi, R.; Struble, T. J.; Payne, J. L.; Vishe, M.; Schley, N. D.; Johnston, J. N.
    \nJ. Am. Chem. Soc.<\/em>, 2019, 141 (1), 618-625.
    \nDOI:     10.1021\/jacs.8b11793<\/a>
    \n\"images_large_ja-2018-117937_0011\"<\/p>\n

  59. Halide metathesis in overdrive: mechanochemical synthesis of a heterometallic group 1 allyl complex<\/strong><\/li>\n

    Koby, R. F.; Rightmire, N. R.; Schley, N. D.; Hanusa, T. P.; Brennessel, W. W.
    \nBeilstein Journal of Organic Chemistry<\/em> 2019, 15, 1856-1863.
    \nDOI:     10.3762\/bjoc.15.181<\/a><\/p>\n

  60. Monometallic lanthanide salicylhydrazone complexes exhibiting strong near-infrared luminescence<\/strong><\/li>\n

    Ayers, K. M.; Schley, N. D.; Ung, G.
    \nChem. Commun.<\/em>, 2019, 55, 8446\u20138449.
    \nDOI:     10.1039\/C9CC03934A<\/a>
    \n\"salicyl\"<\/p>\n

  61. Hydrogen Activation and Hydrogenolysis Facilitated By Late-Transition-Metal\u2013Aluminum Heterobimetallic Complexes.<\/strong><\/li>\n

    Charles, R. M.; Yokley, T. W.; Schley, N. D.; DeYonker, N. J.; Brewster, T. P.
    \nInorganic Chemistry<\/em>, 2019, 58, 12635-12645.
    \nDOI:     10.1021\/acs.inorgchem.9b01359<\/a>
    \n\"images_large_ic9b01359_0011\"<\/p>\n

  62. Synthesis and characterization of rhodium\u2013aluminum heterobimetallic complexes tethered by a 1,3-bis(diphenylphosphino)-2-propanoxy group.<\/strong><\/li>\n

    Li, Z.; Yokley, T. W.; Tran, S. L.; Zong, J.; Schley, N. D.; Brewster, T. P.
    \nDalton Transactions<\/em>, 2019, 48, 8782-8790.
    \nDOI:     10.1039\/C9DT00938H<\/a>
    \n\"tetheredpropanoxy\"<\/p>\n

  63. Solid State Structures, Solution Behavior, and Luminescence of Simple Tetrakis(2-pyridylmethyl)ethylenediamine Lanthanide Complexes.<\/strong><\/li>\n

    Ayers, K. M.; Schley, N. D.; Ung, G.
    \nEuropean Journal of Inorganic Chemistry<\/em>, 2019, 2019, 3769-3775.
    \nDOI:     10.1002\/ejic.201900609<\/a>
    \n\"ejic201900609-toc-0001-m\"<\/p>\n

  64. Absolute Configurations of Naturally Occurring [5]-and [3]-Ladderanoic Acids: Isolation, Chiroptical Spectroscopy and Crystallography<\/strong><\/li>\n

    Raghavan, V.; Johnson, J. L.; Stec, D. F.; Song, B.; Zajac, G.; Baranska, M.; Harris, C. M.; Schley, N. D.; Polavarapu, P. L.; Harris, T. M.
    \nJournal of Natural Products,<\/em> 2018, 81 (12), 2654\u20132666.
    \nDOI:     10.1021\/acs.jnatprod.8b00458<\/a>.
    \n\"images_large_np-2018-00458e_0015\"<\/p>\n

  65. Solvent Dependent Sensitization of Ytterbium and Neodymium via an Intramolecular Excimer<\/strong><\/li>\n

    Deng, M.; Schley, N. D.; Ung, G.
    \nInorg. Chem.<\/em> 2018, 57 (24), pp 15399\u201315405.
    \nDOI:     10.1021\/acs.inorgchem.8b02709<\/a>
    \n\"images_large_ic-2018-02709a_0011\"<\/p>\n

  66. Mechanochemically driven transformations in organotin chemistry: stereochemical rearrangement, redox behavior, and dispersion-stabilized complexes<\/strong><\/li>\n

    Koby, F. R.; Hanusa, T. P.*; Schley, N. D.
    \nJ. Am. Chem. Soc.<\/em>, 2018, 140 (46), pp 15934\u201315942.
    \nDOI:     10.1021\/jacs.8b09862<\/a>
    \n\"images_large_ja-2018-098623_0013\"<\/p>\n

  67. Synthesis, Structure, and Reactivity of Palladium Proazaphosphatrane Complexes Invoked in C\u2013N Cross-Coupling.<\/strong><\/li>\n

    Matthews, A. D.; Gravalis, G. M.; Schley, N. D.; Johnson, M. W.
    \nOrganometallics<\/em> 2018, 37 (18), pp 3073\u20133078.
    \nDOI:     10.1021\/acs.organomet.8b00453<\/a>
    \n\"images_large_om-2018-00453u_0011\"<\/p>\n

  68. Synthesis and Characterization of Heterobimetallic Iridium\u2013Aluminum and Rhodium\u2013Aluminum Complexes<\/strong><\/li>\n

    Brewster, T. P.; Nguyen, T. H.; Li, Z.; Eckenhoff, W. T.; Schley, N. D.; DeYonker, N. J.
    \nInorg. Chem.<\/em> 2018, 57 (3), pp 1148\u20131157.
    \nDOI:     10.1021\/acs.inorgchem.7b02601<\/a>
    \n\"images_large_ic-2017-02601k_0014\"<\/p>\n

    \n

    Prior to Vanderbilt<\/h4>\n
  69. Nickel-Catalyzed Negishi Arylations of Propargylic Bromides: A Mechanistic Investigation.<\/strong><\/li>\n

    Schley, N. D.; Fu, Gregory C.
    \nJ. Am. Chem. Soc.<\/em>, 2014, 136 (47), 16588\u201316593.
    \nDOI:     10.1021\/ja508718m<\/a><\/p>\n

  70. Hydrogen-Transfer Catalysis with Cp*Ir-III Complexes: The Influence of the Ancillary Ligands.<\/strong><\/li>\n

    Hintermair, U.; Campos, J.; Brewster, T. P.; Pratt, L. M.; Schley, N. D.; Crabtree, R. H.
    \nACS Catalysis <\/em>2014, 4, 99\u2013108.
    \nDOI:     10.1021\/cs400834q<\/a><\/p>\n

  71. Domain Structure for an Amorphous Iridium-Oxide Water-Oxidation Catalyst Characterized by X-Ray Pair Distribution Function Analysis.<\/strong><\/li>\n

    Huang, J.; Blakemore, J. D.; Fazi, D.; Kokhan, O.; Schley, N. D.; Crabtree, R. H.; Brudvig, G. W.; Tiede, D. M.
    \nPhys. Chem. Chem. Phys<\/em>. 2014, 16, 1814\u20131819.
    \nDOI:     10.1039\/C3CP54878C<\/a><\/p>\n

  72. Characterization of an Amorphous Iridium Water-Oxidation Catalyst Electrodeposited from Organometallic Precursors.<\/strong><\/li>\n

    Blakemore, J. D.; Mara, M. W.; Kushner-Lenhoff, M. N.; Schley, N. D.; Konezny, S. J.; Rivalta, I.; Negre, C. F. A.; Snoeberger, R. C.; Kokhan, O.; Huang, J.; Stickrath, A.; Tran, L. A.; Parr, M. L.; Chen, L. X.; Tiede, D. M.; Batista, V. S.; Crabtree, R. H.; Brudvig, G. W.
    \nInorg. Chem<\/em>. 2013, 52, 1860\u20131871.
    \nDOI:     10.1021\/ic301968j<\/a><\/p>\n

  73. Effects of Aqueous Buffers on Electrocatalytic Water Oxidation with an Iridium Oxide Material Electrodeposited in Thin Layers from an Organometallic Precursor.<\/strong><\/li>\n

    Kushner-Lenhoff, M. N.; Blakemore, J. D.; Schley, N. D.; Crabtree, R. H.; Brudvig, G. W.
    \nDalton Trans<\/em>. 2013, 42, 3617\u20133622.
    \nDOI:     10.1039\/C2DT32326E<\/a><\/p>\n

  74. Symmetrical Hydrogen Bonds in Iridium(III) Alkoxides with Relevance to Outer Sphere Hydrogen Transfer.<\/strong><\/li>\n

    Schley, N. D.; Halbert, S.; Raynaud, C.; Eisenstein, O.; Crabtree, R. H.
    \nInorg. Chem<\/em>. 2012, 51 (22), 12313\u201313323.
    \nDOI:     10.1021\/ic301601c<\/a><\/p>\n

  75. Mild, Reversible Reaction of Iridium(III) Amido Complexes with Carbon Dioxide.<\/strong><\/li>\n

    Dobereiner, G. E.; Wu, J.; Manas, M. G.; Schley, N. D.; Takase, M. K.; Crabtree, R. H.; Hazari, N.; Maseras, F.; Nova, A.
    \nInorg. Chem<\/em>. 2012, 51 (18), 9683\u20139693.
    \nDOI:     10.1021\/ic300923c<\/a><\/p>\n

  76. A Comparison of Amorphous Iridium Water-Oxidation Electrocatalysts Prepared from Soluble Precursors.<\/strong><\/li>\n

    Blakemore, J. D.; Schley, N. D.; Kushner-Lenhoff, M. N.; Winter, A. M.; D\u2019Souza, F.; Crabtree, R. H.; Brudvig, G. W.
    \nInorg. Chem<\/em>. 2012, 51 (14), 7749\u20137763.
    \nDOI:     10.1021\/ic300764f<\/a><\/p>\n

  77. Ultrafast Photodriven Intramolecular Electron Transfer from an Iridium-Based Water-Oxidation Catalyst to Perylene Diimide Derivatives.<\/strong><\/li>\n

    Vagnini, M. T.; Smeigh, A. L.; Blakemore, J. D.; Eaton, S. W.; Schley, N. D.; D\u2019Souza, F.; Crabtree, R. H.; Brudvig, G. W.; Co, D. T.; Wasielewski, M. R.
    \nProc. Natl. Acad. Sci. U.S.A<\/em>. 2012, 109 (39), 15651\u201315656.
    \nDOI:     10.1073\/pnas.1202075109<\/a><\/p>\n

  78. Characterization of an Activated Iridium Water Splitting Catalyst Using Infrared Photodissociation of H2<\/sub> Tagged Ions.<\/strong><\/li>\n

    Garand, E.; Fournier, J. A.; Kamrath, M. Z.; Schley, N. D.; Crabtree, R. H.; Johnson, M. A.
    \nPhys. Chem. Chem. Phys.<\/em> 2012, 14, 10109\u201310113.
    \nDOI:     10.1039\/C2CP41490B<\/a><\/p>\n

  79. Electron-Rich CpIr(biphenyl-2,2\u2032-diyl) Complexes with \u03c0-Accepting Carbon Donor Ligands.<\/strong><\/li>\n

    Graeupner, J.; Brewster, T. P.; Blakemore, J. D.; Schley, N. D.; Thomsen, J. M.; Brudvig, G. W.; Hazari, N.; Crabtree, R. H.
    \nOrganometallics <\/em>2012, 31, 7158\u20137164.
    \nDOI:     10.1021\/om300696t<\/a><\/p>\n

  80. Axially Chiral Dimeric Ir and Rh Complexes Bridged by Flexible NHC Ligands.<\/strong><\/li>\n

    Ashley, J. M.; Farnaby, J. H.; Hazari, N.*; Kim, K. E.; Luzik Jr, E. D.; Meehan, R, E.; Meyer, E. B.; Schley, N. D.; Schmeier T. J.; Tailor, A. N.
    \nInorg. Chim. Acta<\/em>. 2012, 380, 399\u2013410.
    \nDOI:     10.1016\/j.ica.2011.11.034<\/a><\/p>\n

  81. Oxidative Synthesis of Amides and Pyrroles via Dehydrogenative Alcohol Oxidation by Ruthenium Diphosphine Diamine Complexes.<\/strong><\/li>\n

    Schley, N. D.; Dobereiner, G. E.; Crabtree, R. H.
    \nOrganometallics <\/em>2011, 30 (15), 4174\u20134179.
    \nDOI:     10.1021\/om2004755<\/a><\/p>\n

  82. Distinguishing Homogeneous from Heterogeneous Catalysis in Electrode-Driven Water Oxidation with Molecular Iridium Complexes.<\/strong><\/li>\n

    Schley, N. D.; Blakemore, J. D.; Subbaiyan, N. K.; Incarvito, C. D.; D\u2019Souza, F.; Crabtree, R. H.; Brudvig, G. W.
    \nJ. Am. Chem. Soc<\/em>. 2011, 133 (27), 10473\u201310481.
    \nDOI:     10.1021\/ja2004522<\/a>
    \nHighlighted: Meyer, T. J., Nat. Chem<\/em>. 2011, 3, 757\u2013758. DOI:     10.1038\/nchem.1161<\/a><\/p>\n

  83. Thiocyanate Linkage Isomerism in a Ruthenium Polypyridyl Complex.<\/strong><\/li>\n

    Brewster, T. P.; Ding, W.; Schley, N. D.; Hazari, N.; Batista, V. S.; Crabtree, R. H.
    \nInorg. Chem<\/em>. 2011, 50, 11938\u221211946.
    \nDOI:     10.1021\/ic200950e<\/a><\/p>\n

  84. Iridium-Catalyzed Hydrogenation of N-Heterocyclic Compounds under Mild Conditions by an Outer Sphere Pathway.<\/strong><\/li>\n

    Dobereiner, G. E.; Nova, A.; Schley, N. D.; Hazari, N.; Miller, S. J.; Eisenstein, O.; Crabtree, R. H.
    \nJ. Am. Chem. Soc.<\/em> 2011, 133 (19), 7547\u20137562.
    \nDOI:     10.1021\/ja2014983<\/a><\/p>\n

  85. An Iridium(IV) Species, [Cp*Ir(NHC)Cl]+<\/sup>, Related to a Water-Oxidation Catalyst.<\/strong><\/li>\n

    Brewster, T. P.; Blakemore, J. D.; Schley, N. D.; Incarvito, C. D.; Hazari, N.; Brudvig, G. W.; Crabtree, R. H.
    \nOrganometallics <\/em>2011, 30 (5), 965\u2013973.
    \nDOI:     10.1021\/om101016s<\/a><\/p>\n

  86. An Experimental-Theoretical Study of the Factors That Affect the Switch between Ruthenium-Catalyzed Dehydrogenative Amide Formation versus Amine Alkylation.<\/strong><\/li>\n

    Nova, A.; Balcells, D.; Schley, N. D.; Dobereiner, G. E.; Crabtree, R. H.; Eisenstein, O.
    \nOrganometallics <\/em>2010, 29 (23), 6548\u20136558.
    \nDOI:     10.1021\/om101015u<\/a><\/p>\n

  87. Anodic Deposition of a Robust Iridium-Based Water-Oxidation Catalyst from Organometallic Precursors.<\/strong><\/li>\n

    Blakemore, J. D.; Schley, N. D.; Olack, G. W.; Incarvito, C. D.; Brudvig, G. W.; Crabtree, R. H.
    \nChem. Sci<\/em>. 2011, 2 (1), 94\u201398.
    \nDOI:     10.1039\/C0SC00418A<\/a><\/p>\n

  88. Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis.<\/strong><\/li>\n

    Blakemore, J. D.; Schley, N. D.; Balcells, D.; Hull, J. F.; Olack, G. W.; Incarvito, C. D.; Eisenstein, O.; Brudvig, G. W.; Crabtree, R. H.
    \n J. Am. Chem. Soc<\/em>. 2010, 132 (45), 16017\u201316029.
    \nDOI:     10.1021\/ja104775j<\/a><\/p>\n

  89. Cp* Iridium Complexes Give Catalytic Alkane Hydroxylation with Retention of Stereochemistry.<\/strong><\/li>\n

    Zhou, M.; Schley, N. D.; Crabtree, R. H.
    \nJ. Am. Chem. Soc<\/em>. 2010, 132 (36), 12550\u201312551.
    \nDOI:     10.1021\/ja1058247<\/a><\/p>\n

  90. Acyl Protection Strategy for Synthesis of a Protic NHC Complex via N-Acyl Methanolysis.<\/strong><\/li>\n

    Dobereiner, G. E.; Chamberlin, C. A.; Schley, N. D.; Crabtree, R. H.
    \nOrganometallics <\/em>2010, 29 (21), 5728\u20135731.
    \nDOI:     10.1021\/om100452g<\/a><\/p>\n

  91. Iridium and Ruthenium Complexes with Chelating N-Heterocyclic Carbenes: Efficient Catalysts for Transfer Hydrogenation, beta-Alkylation of Alcohols, and N-Alkylation of Amines.<\/strong><\/li>\n

    Gnanamgari, D.; Sauer, E. L. O.; Schley, N. D.; Butler, C.; Incarvito, C. D.; Crabtree, R. H.
    \nOrganometallics <\/em>2009, 28 (1), 321\u2013325.
    \nDOI:     10.1021\/om800821q<\/a><\/p>\n

  92. Alcohol Cross-Coupling Reactions Catalyzed by Ru and Ir Terpyridine Complexes.<\/strong><\/li>\n

    Gnanamgari, D.; Leung, C. H.; Schley, N. D.; Hilton, S. T.; Crabtree, R. H.
    \nOrg. Biomol. Chem<\/em>. 2008, 6 (23), 4442\u20134445.
    \nDOI:     10.1039\/B815547J<\/a><\/p>\n

  93. Isomeric Forms of Heavier Main Group Hydrides: Experimental and Theoretical Studies of the [Sn(Ar)H]2<\/sub> (Ar=terphenyl) System.<\/strong><\/li>\n

    Rivard, E.; Fischer, R. C.; Wolf, R.; Peng, Y.; Merrill, W. A.; Schley, N. D.; Zhu, Z. L.; Pu, L.; Fettinger, J. C.; Teat, S. J.; Nowik, I.; Herber, R. H.; Takagi, N.; Nagase, S.; Power, P. P.
    \nJ. Am. Chem. Soc<\/em>. 2007, 129 (51), 16197\u201316208.
    \nDOI:     10.1021\/ja076453m<\/a><\/ol>\n","protected":false},"excerpt":{"rendered":"

    Categories Work from our Group Book Chapters and Perspectives Collaborative Publications Prior to Vanderbilt Work from our Group Tandem Oligomerization-Hydrogenation Using Br\u00f8nsted Acidic Iridium Hydride Catalysts Leitgeb, A. J.; Chapp, S. M.; Fast, C. D.; Fink, K. E.; Schley, N. D. Organometallics, 2025. DOI: 10.1021\/acs.organomet.5c00160 Bis(bicyclo[1.1.1]pentyl)chlorophosphine as a Precursor for the Preparation of Bis(bicyclo[1.1.1]pentyl)phosphines Perry,…<\/p>\n","protected":false},"author":4085,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"open","template":"","meta":{"footnotes":""},"tags":[],"class_list":["post-6","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/my.vanderbilt.edu\/schley\/wp-json\/wp\/v2\/pages\/6","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/my.vanderbilt.edu\/schley\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/my.vanderbilt.edu\/schley\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/my.vanderbilt.edu\/schley\/wp-json\/wp\/v2\/users\/4085"}],"replies":[{"embeddable":true,"href":"https:\/\/my.vanderbilt.edu\/schley\/wp-json\/wp\/v2\/comments?post=6"}],"version-history":[{"count":138,"href":"https:\/\/my.vanderbilt.edu\/schley\/wp-json\/wp\/v2\/pages\/6\/revisions"}],"predecessor-version":[{"id":148,"href":"https:\/\/my.vanderbilt.edu\/schley\/wp-json\/wp\/v2\/pages\/6\/revisions\/148"}],"wp:attachment":[{"href":"https:\/\/my.vanderbilt.edu\/schley\/wp-json\/wp\/v2\/media?parent=6"}],"wp:term":[{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/my.vanderbilt.edu\/schley\/wp-json\/wp\/v2\/tags?post=6"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}