{"id":6,"date":"2015-05-15T15:00:17","date_gmt":"2015-05-15T20:00:17","guid":{"rendered":"https:\/\/my.vanderbilt.edu\/timothyhanusa\/publications\/"},"modified":"2022-02-09T22:54:20","modified_gmt":"2022-02-10T03:54:20","slug":"publications","status":"publish","type":"page","link":"https:\/\/my.vanderbilt.edu\/timothyhanusa\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"<p><em><strong><br \/>\nEdited Books<br \/>\n<\/strong><\/em><em>The Lightest Metals: Science and Technology from Lithium to Calcium; <\/em>Hanusa, T. P., Ed; Wiley: Chicester, 2015; 496 pages.<\/p>\n<p><em>The Heaviest\u00a0Metals: Science and Technology of the Actinides and Beyond; <\/em>Evans, W. J.,\u00a0Hanusa, T. P., Ed; Wiley: Chicester, 2019; 496 pages.<\/p>\n<p><em><strong>Publications<\/strong><\/em><em><br \/>\n<\/em> <span style=\"font-size: 13px\">Origin of research: (U) = undergraduate; (G) = graduate; (P) = postdoctoral; (V) = Vanderbilt<\/span><\/p>\n<p><strong>2020\u2013present<\/strong><\/p>\n<p>167. H. P. DeGroot and T. P.; Hanusa, \u201cSolvate-Assisted Grinding: Metal Solvates as Solvent Sources in Mechanochemically Driven Organometallic Reactions,\u201d <i>Organometallics<\/i> <b>2021<\/b>, <i>40<\/i>, 3516\u20133525. doi.org\/10.1021\/acs.organomet.1c00316 (V)<\/p>\n<div id=\"attachment_151\" style=\"width: 156px\" class=\"wp-caption alignright\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-151\" class=\" wp-image-151\" src=\"https:\/\/cdn.vanderbilt.edu\/t2-my\/my-prd\/wp-content\/uploads\/sites\/1774\/2015\/05\/BeInd2-Frontispiece.jpg\" alt=\"Frontispiece ACIE 2021\" width=\"146\" height=\"207\" srcset=\"https:\/\/cdn.vanderbilt.edu\/t2-my\/my-prd\/wp-content\/uploads\/sites\/1774\/2015\/05\/BeInd2-Frontispiece.jpg 595w, https:\/\/cdn.vanderbilt.edu\/t2-my\/my-prd\/wp-content\/uploads\/sites\/1774\/2015\/05\/BeInd2-Frontispiece-212x300.jpg 212w, https:\/\/cdn.vanderbilt.edu\/t2-my\/my-prd\/wp-content\/uploads\/sites\/1774\/2015\/05\/BeInd2-Frontispiece-460x650.jpg 460w\" sizes=\"auto, (max-width: 146px) 100vw, 146px\" \/><p id=\"caption-attachment-151\" class=\"wp-caption-text\">Frontispiece ACIE 2021<\/p><\/div>\n<p>166. R. F. Koby, N. D. Schley, and T. P. Hanusa, \u201cDi(indenyl)beryllium,\u201d <i>Angew. Chem. Int. Ed<\/i>. <b>2021<\/b>, <i>60<\/i>, 21174\u201321178. <a href=\"https:\/\/doi.org\/10.1002\/anie.202107980\">https:\/\/doi.org\/10.1002\/anie.202107980<\/a> (V)<\/p>\n<p>(designated a \u201c<strong>VIP<\/strong>\u201d (Very Important Paper)<\/p>\n<p>165. R. F. Koby, A. M. Doerr, N. R. Rightmire, N. D. Schley, W. W. Brennessel, B. K. Long, T. P. Hanusa, \u201cMechanochemical Formation, Solution Rearrangements, and Catalytic Behavior of a Polymorphic Ca\/K Allyl Complex,\u201d <i>Chem.<\/i> \u2013 <i>Eur. J<\/i>. <b>2021<\/b>, <i>27<\/i>, 8195-8202. https:\/\/doi.org\/10.1002\/chem.202100589 (V)<\/p>\n<p>164. H. P. DeGroot and T. P. Hanusa, \u201cCyano Metal Complexes,\u201d in <i>Encyclopedia of Inorganic Chemistry<\/i>; R. B. King, Ed.; Wiley, <b>2020<\/b>, pp 1-13. (70 references) https:\/\/doi.org\/10.1002\/9781119951438.eibc0055.pub2 (V)<\/p>\n<p>163.\u00a0R. F. Koby, A. M. Doerr, N. R. Rightmire, N. D. Schley, B. K. Long, and T. P. Hanusa, \u201cAn \u03b7<sup>3<\/sup>-Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg\/K Allyl Complex,\u201d <em>Angew. Chem. Int. Ed<\/em>. <strong>2020<\/strong>, <em>59<\/em>, 9542-9548. (V)<\/p>\n<p>162.\u00a0I. R. Speight and T. P. Hanusa, \u201cMechanochemical Activation in Solid-State Fluoro-Grignard Reactions,\u201d <em>Molecules<\/em> <strong>2020<\/strong>, 25, 570. (V)<\/p>\n<p>161. I. R. Speight, I. Huski\u0107, M. Arhangelskis, H. M. Titi, R. S. Stein, T. P. Hanusa, and T. Fri\u0161\u010di\u0107, \u201cDisappearing Polymorphs in Metal\u2013Organic Framework Chemistry: Unexpected Stabilization of a Layered Polymorph over an Interpenetrated Three-Dimensional Structure in Mercury Imidazolate,\u201d <em>Chem.<\/em> \u2013 <em>Eur. J<\/em>. <strong>2020<\/strong>, <em>26<\/em>, 1696-1696. (V)<\/p>\n<p>160. R. F. Koby and T. P. Hanusa, Macrocyclic Complexes of the Alkali Metals. In <i>Reference Module in Chemistry, Molecular Sciences and Chemical Engineering<\/i>, Elsevier: <strong>2020<\/strong>. DOI: <a href=\"https:\/\/doi.org\/10.1016\/B978-0-12-409547-2.14810-3\">https:\/\/doi.org\/10.1016\/B978-0-12-409547-2.14810-3<\/a>. (V)<\/p>\n<p><strong>2015\u20132019<\/strong><\/p>\n<p>159. R. F. Koby and T. P. Hanusa, Lithium, Sodium, Potassium, Rubidium, and Cesium. In <em>Reference Module in Chemistry, Molecular Sciences and Chemical Engineering<\/em>, Elsevier: <strong>2019<\/strong>. DOI: <a href=\"https:\/\/doi.org\/10.1016\/B978-0-12-409547-2.14700-6\">https:\/\/doi.org\/10.1016\/B978-0-12-409547-2.14700-6<\/a>. (V)<\/p>\n<p>158. R. F. Koby, N. R. Rightmire, N. D. Schley, T. P. Hanusa, and W. W. Brennessel, \u201cHalide metathesis in overdrive: mechanochemical synthesis of a heterometallic group 1 allyl complex,\u201d <em>Beilstein J. Org. Chem<\/em>. <strong>2019<\/strong>, <em>15<\/em>, 1856-1863. (V)<\/p>\n<p>157. I. R. Speight, S. C. Chmely, T. P. Hanusa, and A. L. Rheingold, \u201cMechanochemically directed metathesis in Group 2 chemistry: Calcium amide formation without solvent,\u201d <i>Chem. Commun<\/i>., <b>2019<\/b>, <i>55<\/i>, 2202-2205. (V)<\/p>\n<p>156. R. G. Koby, T. P. Hanusa, and N. D. Schley, \u201cMechanochemically Driven Transformations in Organotin Chemistry: Stereochemical Rearrangement, Redox Behavior, and Dispersion-Stabilized Complexes,\u201d <i>J. Am. Chem. Soc<\/i>., <b>2018<\/b>, <i>140<\/i>, 15934-15942. (V)<\/p>\n<p>155. N. C. Boyde, G. W. Steelman, and T. P. Hanusa, \u201cMulticomponent mechanochemical synthesis of cyclopentadienyl titanium <i>tert<\/i>-butoxy halides, Cp<sub>x<\/sub>TiX<sub>y<\/sub>(O<sup>t<\/sup>Bu)<sub>4-(x+y)<\/sub> (x, y = 1, 2; X = Cl, Br),\u201d <i>ACS Omega,<\/i> <b>2018<\/b>, <i>3<\/i>, 8149-8159. (V)<\/p>\n<p>154. R. F. Koby and T. P. Hanusa, \u201cDispersion and Distortion in Heavy Group 2 and Lanthanide Decamethylmetallocenes: the (C<sub>5<\/sub>Me<sub>5<\/sub>)<sub>2<\/sub>(Sr,Sm) Connection,\u201d <i>J. Organomet. Chem.,<\/i> <b>2018<\/b>, 857, 145-151. (V)<\/p>\n<p>153. N. C. Boyde, N. R. Rightmire, T. P. Hanusa, and W. W. Brennessel, \u201cSymmetric Assembly of a Sterically Encumbered Allyl Complex: Mechanochemical and Solution Synthesis of the Tris(allyl)beryllate, K[BeA\u00b4<sub>3<\/sub>] (A\u00b4 = 1,3-(SiMe<sub>3<\/sub>)<sub>2<\/sub>C<sub>3<\/sub>H<sub>3<\/sub>),\u201d\u00a0<i>Inorganics,<\/i> <b>2017<\/b>, <i>5<\/i>, 36. <a href=\"http:\/\/www.mdpi.com\/2304-6740\/5\/2\/36\">http:\/\/www.mdpi.com\/2304-6740\/5\/2\/36<\/a> (V)<\/p>\n<p>152. N. C. Boyde, N. R. Rightmire, E. J. Bierschenk, G. W. Steelman, T. P. Hanusa, and W. W.\u00a0Brennessel, \u201cReaction environment and ligand lability in group 4 Cp<sub>2<\/sub>MXY (X, Y = Cl, OtBu) complexes,\u201d <em>Dalton Trans<\/em>. <strong>2016<\/strong>, <em>45<\/em>, 18635\u201318642. (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1039\/C6DT03199D\">http:\/\/dx.doi.org\/10.1039\/C6DT03199D<\/a><\/p>\n<div id=\"attachment_135\" style=\"width: 155px\" class=\"wp-caption alignright\"><a href=\"https:\/\/cdn.vanderbilt.edu\/t2-my\/my-prd\/wp-content\/uploads\/sites\/1774\/2015\/05\/Cover-NJCOrg-00001.jpg\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-135\" class=\"wp-image-135\" src=\"https:\/\/cdn.vanderbilt.edu\/t2-my\/my-prd\/wp-content\/uploads\/sites\/1774\/2015\/05\/Cover-NJCOrg-00001.jpg\" alt=\"Cover, Oct 2016 NJC\" width=\"145\" height=\"190\" \/><\/a><p id=\"caption-attachment-135\" class=\"wp-caption-text\">Cover, Oct 2016 NJC<\/p><\/div>\n<p>151. L. S. Fitts, E. J. Bierschenk, T. P. Hanusa, A. L. Rheingold, M. Pink, and V. G. Young, &#8220;Selective modification of the metal coordination environment in heavy alkaline-earth iodide complexes,&#8221;\u00a0<em>New J. Chem<\/em>. <strong>2016<\/strong>, <em>40<\/em>, 8229\u20138238. (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1039\/C6NJ01713D\">http:\/\/dx.doi.org\/10.1039\/C6NJ01713D<\/a><\/p>\n<p>150. N. R.\u00a0Rightmire, D. L. Bruns, T. P. Hanusa, and W. W. Brennessel, \u201cMechanochemical Influence on the Stereoselectivity of Halide Metathesis: Synthesis of Group 15 Tris(allyl) ComplexesComplexes,\u201d\u00a0<em>Organometallics<\/em>,\u00a0<strong>2016<\/strong>,\u00a0<em>35<\/em>, 1698\u20131706. (V)\u00a0<a href=\"http:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.organomet.6b00151\">http:\/\/pubs.acs.org\/doi\/full\/10.1021\/acs.organomet.6b00151<\/a><\/p>\n<p>149. N. R. Rightmire and T. P. Hanusa, \u201cAdvances in Organometallic Synthesis with Mechanochemical Methods,\u201d\u00a0<em>Dalton Trans.,<\/em><strong>2016,<\/strong><strong>\u00a0<\/strong><span>2352-2362. (V)\u00a0<\/span><a href=\"http:\/\/dx.doi.org\/10.1039\/C5DT03866A\">http:\/\/dx.doi.org\/10.1039\/C5DT03866A<\/a>\u00a0\u00a0\u00a0<a href=\"https:\/\/cdn.vanderbilt.edu\/t2-my\/my-prd\/wp-content\/uploads\/sites\/1774\/2015\/05\/image.jpeg\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone  wp-image-149\" src=\"https:\/\/cdn.vanderbilt.edu\/t2-my\/my-prd\/wp-content\/uploads\/sites\/1774\/2015\/05\/image-650x101.jpeg\" alt=\"image\" width=\"116\" height=\"18\" srcset=\"https:\/\/cdn.vanderbilt.edu\/t2-my\/my-prd\/wp-content\/uploads\/sites\/1774\/2015\/05\/image-650x104.jpeg 650w, https:\/\/cdn.vanderbilt.edu\/t2-my\/my-prd\/wp-content\/uploads\/sites\/1774\/2015\/05\/image-300x47.jpeg 300w, https:\/\/cdn.vanderbilt.edu\/t2-my\/my-prd\/wp-content\/uploads\/sites\/1774\/2015\/05\/image.jpeg 667w\" sizes=\"auto, (max-width: 116px) 100vw, 116px\" \/><\/a>\u00a0(Thomsen Reuters)<\/p>\n<p>148. T P. Hanusa, \u201cMetal-based NMR Spectroscopy in Solution,\u201d in <em>The Lightest Metals: Science and Technology from Lithium to Calcium<\/em>; T. P. Hanusa, Ed.; Wiley: Chichester, <strong>2015<\/strong>, pp 91-116. (V)\u00a0<a href=\"http:\/\/DOI: 10.1002\/9781119951438.eibc2292\">http:\/\/DOI: 10.1002\/9781119951438.eibc2292<\/a><\/p>\n<p>147. N. C. Boyde and T P. Hanusa, \u201cInterrelationships Between the Lightest Metals,\u201d in <em>The Lightest Metals: Science and Technology from Lithium to Calcium<\/em>; T. P. Hanusa, Ed.; Wiley: Chichester, <strong>2015<\/strong>, pp 3-22. (V)\u00a0<a href=\"http:\/\/DOI: 10.1002\/9781119951438.eibc2288\">http:\/\/DOI: 10.1002\/9781119951438.eibc2288<\/a><\/p>\n<p><strong>2010\u20132014<\/strong><\/p>\n<p>146. T. P. Hanusa, \u201cAlkaline Earth Organometallics,\u201d in <em>Reference Module in Chemistry, Molecular Sciences and Engineering<\/em>; Reedijk, J., Ed.; Elsevier: Oxford, <strong>2014<\/strong>. <a href=\"http:\/\/DOI:10.1016\/B978-0-12-409547-2.10982-5\">DOI:10.1016\/B978-0-12-409547-2.10982-5<\/a>. (V)<\/p>\n<p>145. T. P. Hanusa, \u201cGroup 1<em>s<\/em> and 2<em>s<\/em> Metals,\u201d in <em>Reference Module in Chemistry, Molecular Sciences and Engineering<\/em>; Reedijk, J., Ed.; Elsevier: Oxford, <strong>2014<\/strong>. <a href=\"http:\/\/DOI:10.1016\/B978-0-12-409547-2.10973-4\">DOI:10.1016\/B978-0-12-409547-2.10973-4 <\/a>(V)<\/p>\n<p>144. N. R. Rightmire, T. P. Hanusa, A. L. Rheingold, \u201cMechanochemical Synthesis of [1,3-(SiMe<sub>3<\/sub>)<sub>2<\/sub>C<sub>3<\/sub>H<sub>3<\/sub>]<sub>3<\/sub>(Al,Sc), a Base-Free Tris(allyl)aluminum Complex and Its Scandium Analogue,\u201d <em>Organometallics <\/em><strong>2014,<\/strong> <em>33<\/em>, 5952\u20135955. (V) (<strong>ACS Editors\u2019 Choice<\/strong> article)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/om5009204\">http:\/\/dx.doi.org\/10.1021\/om5009204<\/a><\/p>\n<p>143. N. R. Rightmire, K. T. Quisenberry, and T. P. Hanusa, \u201cBalancing Adduct Formation and Ligand Coupling with the Bulky Allyl Complexes [1,3-(SiMe<sub>3<\/sub>)<sub>2<\/sub>C<sub>3<\/sub>H<sub>3<\/sub>]<sub>2<\/sub>M (M = Fe, Co, Ni),\u201d <em>Organometallics<\/em>, <strong>2014<\/strong>, <em>33<\/em> , 5678\u20135685. (V)\u00a0<a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/om5004573\">http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/om5004573<\/a><\/p>\n<p>142. N. C. Boyde, S. C. Chmely, T. P. Hanusa, A. L. Rheingold, and W. W. Brennessel, \u201cStructural Distortions in M[E(SiMe<sub>3<\/sub>)<sub>2<\/sub>]<sub>3<\/sub> Complexes (M = Group 15, f-Element; E = N, CH): Is Three a Crowd?\u201d <em>Inorg. Chem. <\/em><strong>2014,<\/strong> <em>53<\/em>, 9703-9714. (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ic501232z\">http:\/\/dx.doi.org\/10.1021\/ic501232z<\/a><\/p>\n<p>141. T. P. Hanusa, E. J. Bierschenk, L. K. Engerer, K. A. Martin, and N. R. Rightmire, \u201cSynthesis and Structures of Group 2 Compounds,\u201d in <em>Comprehensive Inorganic Chemistry-II<\/em>; Reedijk, J., Poeppelmeier, K., Eds; Elsevier: Oxford, <strong>2013<\/strong>, Vol. 1, pp. 1133-1187. (405 references) (V)\u00a0<a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/B9780080977744001455\">http:\/\/www.sciencedirect.com\/science\/article\/pii\/B9780080977744001455<\/a><\/p>\n<p>140. T. P. Hanusa, \u201cBarium: physical and chemical properties,\u201d in <em>Encyclopedia of Metalloproteins<\/em>; R. H. Kretsinger, V. N. Uversky, and E. A. Permyakov, Eds.; Springer, <strong>2013<\/strong>; pp 244\u2013250.\u00a0 (10 references) (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1007\/978-1-4614-1533-6_167\">http:\/\/dx.doi.org\/10.1007\/978-1-4614-1533-6_167<\/a><\/p>\n<p>139. T. P. Hanusa, \u201cStrontium: physical and chemical properties,\u201d in <em>Encyclopedia of Metalloproteins<\/em>; R. H. Kretsinger, V. N. Uversky, and E. A. Permyakov, Eds.; Springer, <strong>2013<\/strong>; pp 2141\u20132149.\u00a0 (10 references) (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1007\/978-1-4614-1533-6_174\">http:\/\/dx.doi.org\/10.1007\/978-1-4614-1533-6_174<\/a><\/p>\n<p>138. C. Lichtenberg, T. P. Spaniol, I. Peckermann, T. P. Hanusa, and \u00a0J. Okuda, \u201cCationic, Neutral, and Anionic Allyl Magnesium Compounds: Unprecedented Ligand Conformations and Reactivity Toward Unsaturated Hydrocarbons,\u201d <em>J. Am. Chem. Soc. <\/em><strong>2013,<\/strong> <em>135<\/em>, 811-821. (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ja310112e\">http:\/\/dx.doi.org\/10.1021\/ja310112e<\/a><\/p>\n<p>137. T. P. Hanusa, \u201cRadium,\u201d in <em>Encyclopaedia Britannica Online<\/em> (2012) (<a href=\"http:\/\/www.britannica.com\/ science\/radium\">www.britannica.com\/ science\/radium<\/a>) (V)<\/p>\n<p>136. T. P. Hanusa, \u201cBarium,\u201d in <em>Encyclopaedia Britannica Online<\/em> (2012) (<a href=\"http:\/\/www.britannica.com\/ science\/barium\">www.britannica.com\/ science\/barium<\/a>) (V)<\/p>\n<p>135. T. P. Hanusa, \u201cStrontium,\u201d in <em>Encyclopaedia Britannica Online<\/em> (2012) (<a href=\"http:\/\/www.britannica.com\/ science\/strontium\">www.britannica.com\/ science\/strontium<\/a>) (V)<\/p>\n<p>134. T. P. Hanusa, \u201cCalcium,\u201d in <em>Encyclopaedia Britannica Online<\/em> (2012) (<a href=\"http:\/\/www.britannica.com\/ science\/calcium\">www.britannica.com\/ science\/calcium<\/a>) (V)<\/p>\n<p>133. T. P. Hanusa, \u201cMagnesium,\u201d in <em>Encyclopaedia Britannica Online<\/em> (2012) (<a href=\"http:\/\/www.britannica.com\/ science\/magnesium\">www.britannica.com\/ science\/magnesium<\/a>) (V)<\/p>\n<p>132. T. P. Hanusa, \u201cBeryllium,\u201d in <em>Encyclopaedia Britannica Online<\/em> (2012) (<a href=\"http:\/\/www.britannica.com\/ science\/beryllium\">www.britannica.com\/ science\/beryllium<\/a>) (V)<\/p>\n<p>131. C. S. G. Phillips and T. P. Hanusa, \u201cAlkaline-earth metal,\u201d in\u00a0<em>Encyclopaedia Britannica Online<\/em>(2012) (<a href=\"http:\/\/www.britannica.com\/science\/alkaline-earth-metal\">www.britannica.com\/science\/alkaline-earth-metal<\/a>) (V)<\/p>\n<p>130. L. K. Engerer; C. N. Carlson; T. P. Hanusa; W. W. Brennessel; V. G. Young, Jr., \u201c\u03c3- vs \u03c0-Bonding in Manganese(II) Allyl Complexes,\u201d <em>Organometallics <\/em><strong>2012,<\/strong> <em>31<\/em>, 6131-6138. (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/om300478v\">http:\/\/dx.doi.org\/10.1021\/om300478v<\/a><\/p>\n<p>129. R. M. Meier and T. P. Hanusa, \u201cStructural organomanganese chemistry,\u201d in <em>The chemistry of organomanganese compounds<\/em>; Z. Rappoport and I. Marek, Eds.; Patai\u2019s Chemistry of Functional Groups; Wiley, <strong>2011<\/strong>; pp 1\u2013127. (450 references) (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1002\/9780470682531.pat0541\">http:\/\/dx.doi.org\/10.1002\/9780470682531.pat0541<\/a><\/p>\n<p>128. R. M. Meier and T. P. Hanusa, \u201cSymmetry and\u00a0Steric Effects on Spin States in Transition Metal Complexes,\u201d in <em>Encyclopedia of Inorganic Chemistry-II (Online Edition)<\/em>; R. A. Scott, Ed.; John Wiley: Chichester, <a href=\"http:\/\/DOI: 10.1002\/9781119951438.eibc0704\">http:\/\/DOI: 10.1002\/9781119951438.eibc0704<\/a>. Published 15th June 2011 (38 references) (V)<\/p>\n<p>127. E. J. Bierschenk, N. R. Wilk, Jr., and T. P. Hanusa, \u201c2,4-Pentanediolate as an Alkoxide\/Diketonate \u201cHybrid\u201d Ligand and the Formation of Aluminum and Zirconium Derivatives,\u201d <em>Inorg. Chem<\/em>., <strong>2011,<\/strong> <em>50<\/em>, 12126-12132. (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ic201718a\">http:\/\/dx.doi.org\/10.1021\/ic201718a<\/a><\/p>\n<p>126. P. Jochmann, T. P. Spaniol, S. C. Chmely, T. P. Hanusa, and J. Okuda, \u201cPreparation, Structure, and Ether Cleavage of a Mixed Hapticity Allyl Compound of Calcium,\u201d <em>Organometallics <\/em><strong>2011,<\/strong> <em>30<\/em>, 5291-5296. (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/om200749f\">http:\/\/dx.doi.org\/10.1021\/om200749f<\/a><\/p>\n<p>125. L. K. Engerer and T. P. Hanusa,\u00a0 \u201cGeometric Effects in Olefinic Cation-\u03c0 Interactions with Alkali Metals: A Computational Study,\u201d <em>J. Org. Chem.,<\/em> <strong>2011,<\/strong> <em>76<\/em>, 42-49. (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/jo101307z\">http:\/\/dx.doi.org\/10.1021\/jo101307z<\/a><\/p>\n<p>124. S. C. Chmely and T. P. Hanusa, \u201cd- and f-Block Transition Metal Complexes with Bulky Allyl Ligands,\u201d in <em>Encyclopedia of Inorganic Chemistry-II (Online Edition)<\/em>; R. H. Crabtree, Ed.; John Wiley: Chichester. <a href=\"http:\/\/DOI: 10.1002\/9781119951438.eibc0279.pub2\">DOI: 10.1002\/0470862106.ia299.pub2<\/a>. Published 15th December 2010. (38 references) (V)<\/p>\n<p>123. C. H. McMillen, C. K. Gren, T. P. Hanusa, and A. L. Rheingold, \u201cA Tetrameric Allyl Complex of Sodium, and Computational Modeling of the <sup>23<\/sup>Na\u2013Allyl Chemical\u00a0Shift,\u201d <em>Inorg. Chim. Acta,<\/em> <strong>2010<\/strong>, <em>364<\/em>, 61\u201368. 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Hanusa, \u201cTrends in the Structures and Energetics of the Group 14 Metallocenes (C<sub>5<\/sub><span style=\"font-size: 13px\">H<\/span><sub>5<\/sub><span style=\"font-size: 13px\">)<\/span><sub>2<\/sub><span style=\"font-size: 13px\">M (M = Si\u2013Pb): a Density Functional Theory Study,\u201d<\/span><em>Organometallics<\/em><span style=\"font-size: 13px\">,<\/span><strong>2001<\/strong><span style=\"font-size: 13px\">,\u00a0<\/span><em>20<\/em><span style=\"font-size: 13px\">, 3056-3062. (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/om020082v\">http:\/\/dx.doi.org\/10.1021\/om020082v<\/a><\/span><\/p>\n<p>81. J. D. Smith, T. P. Hanusa, and V. G. Young, Jr., \u201cSteric Stabilization of Homoleptic Bis(\u03c0\uf070-allyl) Complexes of Chromium(II) and Iron(II),\u201d <em>J. Am. Chem. Soc.<\/em>, <strong>2001<\/strong>, <em>123<\/em>, 6455-6456. (V) <a href=\"http:\/\/dx.doi.org\/10.1021\/ja015626j\">http:\/\/dx.doi.org\/10.1021\/ja015626j<\/a><\/p>\n<p>80. M. J. Harvey. T. P. 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Burkey, \u201cCyano Metal Complexes,\u201d in <em>Encyclopedia of Inorganic Chemistry<\/em>; R. B. King, Ed.; Wiley, <strong>1994<\/strong>, <em>2<\/em>, pp 943-949. (34 references) (V) (No online link available)<\/p>\n<p>48. T. P. Hanusa, \u201cCalcium, Strontium &amp; Barium: Organometallic Chemistry,\u201d in <em>Encyclopedia of Inorganic Chemistry<\/em>; R. B. King, Ed.; Wiley, <strong>1994<\/strong>, <em>1<\/em>, pp 507-518. (120 references) (V)\u00a0(No online link available)<\/p>\n<p>47. J. S. Overby and T. P. Hanusa, \u201cSynthesis and Crystal Structure of the \u201cOpen\u201d Calcocene, [{(<em>t<\/em>Bu)<sub>2<\/sub>C<sub>5<\/sub>H<sub>5<\/sub>}<sub>2<\/sub>Ca\u2022thf],\u201d <em>Angew. Chem. Int. Ed. Engl.,<\/em> <strong>1994<\/strong>, <em>33<\/em>, 2191-2193. (V) (Selected for inclusion in a \u201cHighlights\u201d article for the issue)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1002\/anie.199421911\">http:\/\/dx.doi.org\/10.1002\/anie.199421911<\/a><\/p>\n<p>46. P. S. Tanner and T. P. Hanusa, \u201cEncapsulated Alkaline-earth Metallocenes. 4. Thermal Instability in Tetraphenylcyclopentadienyl Barium Complexes,\u201d <em>Polyhedron<\/em>, <strong>1994<\/strong>, <em>13<\/em>, 2417-2420. (V)\u00a0<a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0277538700881541\">http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0277538700881541<\/a><\/p>\n<p>45. J. A. Burman, M. L. Hays, D. J. Burkey, P. S. Tanner, and T. P. Hanusa, \u201dSynthesis and Structural Characterization of Hexa(cyclohexyl)ferrocene, [1,2,4-(C<sub>6<\/sub>H<sub>11<\/sub>)<sub>3<\/sub>C<sub>5<\/sub>H<sub>2<\/sub>]<sub>2<\/sub>Fe,\u201d <em>J. Organomet. Chem.<\/em>, <strong>1994<\/strong>, <em>479<\/em>, 135-139. (V)\u00a0<a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/0022328X94841004\">http:\/\/www.sciencedirect.com\/science\/article\/pii\/0022328X94841004<\/a><\/p>\n<p>44. D. J. Burkey, E. K. Alexander and T. P. Hanusa, \u201cEncapsulated Alkaline-Earth Metallocenes. 5. Kinetic Stabilization of Mono[tetraisopropylcyclopentadienyl]calcium Complexes,\u201d <em>Organometallics<\/em>, <strong>1994<\/strong>, <em>13<\/em>, 2773-2786. (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/om00019a038\">http:\/\/dx.doi.org\/10.1021\/om00019a038<\/a><\/p>\n<p>43. J. J. Molenda, M. A. Basinger, T. P. Hanusa and M. M. Jones, \u201cSynthesis and Iron(III) Binding Properties of 3-Hydroxypyrid-4-ones Derived from Kojic Acid,\u201d <em>J. Inorg. Biochem.<\/em>, <strong>1994<\/strong>, <em>55<\/em>, 131-146. (V)\u00a0<a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/0162013494850356\">http:\/\/www.sciencedirect.com\/science\/article\/pii\/0162013494850356<\/a><\/p>\n<p>42. K. F. Tesh, D. J. Burkey and T. P. Hanusa, \u201cFormation, Structures and Reactions of Calcium and Barium Mono(alkoxide) Complexes,\u201d <em>J. Am. Chem. Soc.<\/em>, <strong>1994<\/strong>, <em>116<\/em>, 2409-2417. 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Rev.<\/em>, <strong>1993<\/strong>, <em>93<\/em>, 1023-1036. (V) (Invited review with 164 references)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/cr00019a009\">http:\/\/dx.doi.org\/10.1021\/cr00019a009<\/a><\/p>\n<p>38. D. J. Burkey, R. A. Williams, and T. P. Hanusa, \u201cEncapsulated Alkaline-earth Metallocenes. 2. Triisopropylcyclopentadienyl Systems, [(C<sub>3<\/sub>H<sub>7<\/sub>)<sub>3<\/sub>C<sub>5<\/sub>H<sub>2<\/sub>]<sub>2<\/sub>Ae(THF)<sub>n<\/sub> (Ae = Ca, Sr, Ba; n = 0\u20132) and the Crystal Structure of [(C<sub>3<\/sub>H<sub>7<\/sub>)<sub>3<\/sub>C<sub>5<\/sub>H<sub>2<\/sub>]<sub>2<\/sub>Ba(THF)<sub>2<\/sub>,\u201d <em>Organometallics<\/em>, <strong>1993<\/strong>, <em>12<\/em>, 1331-1337. (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/om00028a056\">http:\/\/dx.doi.org\/10.1021\/om00028a056<\/a><\/p>\n<p>37. K. F. Tesh, T. P. Hanusa, J. C. Huffman, and C. J. 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Hanusa, \u201cSolution Synthesis of Calcium, Strontium, and Barium Metallocenes,\u201d <em>Polyhedron<\/em> <strong>1988<\/strong>, <em>7(9)<\/em>, 725-730. (V)\u00a0<a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0277538788800457\">http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0277538788800457<\/a><\/p>\n<p>19. \u00a0W. J. Evans, M. S. Sollberger, and T. P. Hanusa, \u201cSynthesis and Structure of the Polymetallic Yttrium Alkoxide Complex, Y<sub>3<\/sub>(\u00b5<sub>3<\/sub>-OCMe<sub>3<\/sub>)(\u00b5<sub>3<\/sub>-Cl)(\u00b5-OCMe<sub>3<\/sub>)<sub>3<\/sub>(OCMe<sub>3<\/sub>)<sub>4<\/sub>(THF)<sub>2<\/sub> and Related Complexes: Ln<sub>3<\/sub>(\u00b5<sub>3<\/sub>-OR)(\u00b5<sub>3<\/sub>-X)(\u00b5-OR)<sub>3<\/sub> Building Blocks in Yttrium and Lanthanide Alkoxide Chemistry,\u201d <em>J. Am. Chem. Soc.<\/em> <strong>1988<\/strong>, <em>110<\/em>, 1841-1850. (P)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ja00214a029\">http:\/\/dx.doi.org\/10.1021\/ja00214a029<\/a><\/p>\n<p>18. T. P. Hanusa, N. R. de Parisi, J. G. Kester, A. Arafat, and L. J. Todd, \u201cSynthesis of Polyhedral Arsaboranes and Their Metal Derivatives,\u201d <em>Inorg. Chem<\/em>. <strong>1987<\/strong>, <em>26<\/em>, 4100-4102. (G)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ic00271a026\">http:\/\/dx.doi.org\/10.1021\/ic00271a026<\/a><\/p>\n<p>17. W. J. Evans, D. K. Drummond, T. P. Hanusa and R. J. Doedens, \u201cBis(1,2-dimethylcyclo\u00adpentadienyl) Yttrium Complexes. Synthesis and X-ray Crystallographic Characterization of [(1,3-Me<sub>2<\/sub>C<sub>5<\/sub>H<sub>3<\/sub>)<sub>2<\/sub>Y(\u00b5-Me)]<sub>2<\/sub>, [(1,3-Me<sub>2<\/sub>C<sub>5<\/sub>H<sub>3<\/sub>)<sub>2<\/sub>Y(\u00b5-H)]<sub>3<\/sub>, and [(1,3-Me<sub>2<\/sub>C<sub>5<\/sub>H<sub>3<\/sub>)<sub>2<\/sub>(THF)Y(\u00b5-H)]<sub>2<\/sub>,\u201d <i>Organometallics<\/i> <b>1987<\/b>, <i>6<\/i>, 2279-2285. (P)<\/p>\n<p>16. T. P. Hanusa, \u201cReexamining the Diagonal Relationships,\u201d <em>J. Chem. Educ.<\/em><strong>1987<\/strong>,\u00a0<em>64(8)<\/em>, 686-687. (V)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ed064p686\">http:\/\/dx.doi.org\/10.1021\/ed064p686<\/a><\/p>\n<p>15. \u00a0W. J. Evans, T. P. Hanusa, J. H. Meadows, W. E. Hunter, and J. L. Atwood, \u201cSynthesis and X-ray Crystal Structure of \u00b5,\u03b7<sup>2<\/sup>&#8211;<em>N<\/em>-Alkylformimidoyl\u00a0Complexes of Erbium and Yttrium, A Structural Comparison,\u201d <em>Organometallics<\/em> <strong>1987<\/strong>, <em>6<\/em>, 295-301. (P)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/om00145a010\">http:\/\/dx.doi.org\/10.1021\/om00145a010<\/a><\/p>\n<p>14. W. J. Evans, R. Dominguez, and T. P. Hanusa, \u201cOrganolanthanide and Organoyttrium Enolate Chemistry. The Synthesis of [(C<sub>5<\/sub>H<sub>4<\/sub>R)<sub>2<\/sub>Ln(\u00b5-OCH=CH<sub>2<\/sub>)]<sub>2<\/sub> and the Molecular Structure of [(CH<sub>3<\/sub>C<sub>5<\/sub>H<sub>4<\/sub>)<sub>2<\/sub>Y(\u00b5-OCH=CH<sub>2<\/sub>)]<sub>2<\/sub>,\u201d<em>Organometallics<\/em> <strong>1986<\/strong>, <em>5<\/em>, 1291-1296. (P)<\/p>\n<p>13. \u00a0W. J. Evans, L. A. Hughes, T. P. Hanusa, and R. J. Doedens, \u201cSynthesis and X-ray Crystal Structures of Bis(pentamethylcyclopentadienyl) Complexes of Samarium and Europium, (C<sub>5<\/sub>Me<sub>5<\/sub>)<sub>2<\/sub>Sm and (C<sub>5<\/sub>Me<sub>5<\/sub>)<sub>2<\/sub>Eu,\u201d <em>Organometallics<\/em> <strong>1986<\/strong>, <em>5<\/em>, 1285-1291. (P)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/om00138a001\">http:\/\/dx.doi.org\/10.1021\/om00138a001<\/a><\/p>\n<p>12. T. P. Hanusa and W. J. Evans, \u201cX-ray Crystal Structure of Solvent-free Hydrido\u00adtris(triphenylphosphine)rhodium, HRh(PPh<sub>3<\/sub>)<sub>3<\/sub>,\u201d <em>J. Coord. Chem<\/em>. <strong>1986<\/strong>, <em>14<\/em>, 223-229. (P)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1080\/00958978608073911\">http:\/\/dx.doi.org\/10.1080\/00958978608073911<\/a><\/p>\n<p>11. \u00a0W. J. Evans, R. Dominguez, and T. P. Hanusa, \u201cOrganolanthanide and organoyttrium hydride chemistry. Part 8.\u00a0Structure and Reactivity Studies of Bis\u00ad(cyclopentadienyl) Ytterbium and Yttrium Alkyl Complexes Including the X-ray Crystal Structure of (C<sub>5<\/sub>H<sub>5<\/sub>)<sub>2<\/sub>Yb(CH<sub>3<\/sub>)(THF),\u201d <em>Organometallics<\/em> <strong>1986<\/strong>, <em>5<\/em>, 263-270. (P)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/om00133a016\">http:\/\/dx.doi.org\/10.1021\/om00133a016<\/a><\/p>\n<p>10. T. P. Hanusa and L. J. Todd, \u201cReductive Isomerization of Icosahedral Metallocarbaboranes,\u201d <em>Polyhedron<\/em> <strong>1985<\/strong>,<em> 4<\/em>, 2063-2066. (G)\u00a0<a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0277538700867364\">http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0277538700867364<\/a><\/p>\n<p>9. W. J. Evans, T. P. Hanusa, and K. R. Levan, \u201cSynthesis and Structure of an Organosamarium Aryloxide Complex, (C<sub>5<\/sub>Me<sub>5<\/sub>)<sub>2<\/sub>Sm(OC<sub>6<\/sub>HMe<sub>4<\/sub>-2,3,5,6),\u201d <em>Inorg. Chem. Acta <\/em><strong>1985<\/strong>,<em> 110<\/em>, 191-195. (P)\u00a0<a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0020169300823063\">http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0020169300823063<\/a><\/p>\n<p>8. T. P. Hanusa, T. A. Ulibarri, and W. J. Evans, \u201cStructure of (h-Methylcyclopentadienyl)(tri\u00adphenylphosphine)copper(I), [Cu(CH<sub>3<\/sub>C<sub>5<\/sub>H<sub>4<\/sub>){P(C<sub>6<\/sub>H<sub>5<\/sub>)<sub>3<\/sub>}],\u201d<em> Acta. Crystallogr.<\/em> <strong>1985<\/strong>, <em>C<\/em>41, 1036-1038. (P)\u00a0<a href=\"https:\/\/doi.org\/10.1107\/S0108270185006485\">https:\/\/doi.org\/10.1107\/S0108270185006485<\/a><\/p>\n<p>7. T. P. Hanusa, T. L. Curtis, J. C. Huffman, and L. J. Todd, \u201cSynthesis of (\u03c0-Arene)\u00admetallocarbaboranes Containing Ruthenium or Osmium and a (\u03c0-Cyclohexadienyl)cobalta\u00adcarbaborane. Crystal Structure of 2,5,6-(\u03b7-C<sub>6<\/sub>H<sub>6<\/sub>)RuC<sub>2<\/sub>B<sub>7<\/sub>H<sub>11<\/sub>,\u201d <em>Inorg. Chem<\/em>. <strong>1985<\/strong>, 24, 787-792. (G)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ic00199a032\">http:\/\/dx.doi.org\/10.1021\/ic00199a032<\/a><\/p>\n<p><strong>1980\u20131984<\/strong><\/p>\n<p>5. W. J. Evans, L. A. Hughes, and T. P. Hanusa, \u201cSynthesis and Crystallographic Characterization of an Unsolvated, Monomeric Bis(pentamethylcyclopentadienyl) Organolanthanide Complex, (C<sub>5<\/sub>Me<sub>5<\/sub>)<sub>2<\/sub>Sm,\u201d <em>J. Am. Chem. Soc.<\/em> <strong>1984<\/strong>, <em>106<\/em>, 4270-4272. (P)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ja00327a037\">http:\/\/dx.doi.org\/10.1021\/ja00327a037<\/a><\/p>\n<p>4. T. P. Hanusa, \u201cPentamethylcyclopentadiene and the Carbaborane B<sub>9<\/sub>C<sub>2<\/sub>H<sub>11<\/sub><sup>2-<\/sup> as Analogous Ligands in Transition Metal Complexes,\u201d <em>Polyhedron<\/em> <strong>1982<\/strong>, <em>1<\/em>, 663-665. (G)\u00a0<a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0277538700808657\">http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0277538700808657<\/a><\/p>\n<p>3. T. P. Hanusa, J. C. Huffman, and L. J. Todd, \u201cSynthesis of \u03c0-(Arene)metallocarboranes Containing Iron and Ruthenium. Crystal Structure of 3,1,2-(\u03b7<sup>6<\/sup>-1,3,5-(CH<sub>3<\/sub>)<sub>3<\/sub>C<sub>6<\/sub>H<sub>3<\/sub>)FeC<sub>2<\/sub>B<sub>9<\/sub>H<sub>11<\/sub>,\u201d<em> Polyhedron<\/em> <strong>1982<\/strong>,<em> 1<\/em>, 77-82. (G)\u00a0<a href=\"http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0277538700810724\">http:\/\/www.sciencedirect.com\/science\/article\/pii\/S0277538700810724<\/a><\/p>\n<p>2. A. M. Barriola, T. P. Hanusa, and L. J. Todd, \u201cSynthesis of Heteroatom Boranes Containing Two Arsenic Atoms,\u201d<em> Inorg. Chem.<\/em> <strong>1980<\/strong>, <em>19,<\/em> 2801-2802. (G)\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/ic50211a061\">http:\/\/dx.doi.org\/10.1021\/ic50211a061<\/a><\/p>\n<p>1. T. H. Jordan, J. S. Wefel, D. Brennan, C. Brooks, T. Hanusa, S. VanWhy, \u201cReaction Between TiF<sub>4<\/sub>and Apatite,\u201d\u00a0<em>J. Dent. Res<\/em>.\u00a0<strong>1980<\/strong>,\u00a0<em>59<\/em>(<em>Sp. Iss. A<\/em>), 523. (U)\u00a0(No online link available)<\/p>\n<p><span style=\"font-size: 13px\"><br \/>\n<\/span><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Edited Books The Lightest Metals: Science and Technology from Lithium to Calcium; Hanusa, T. P., Ed; Wiley: Chicester, 2015; 496 pages. The Heaviest\u00a0Metals: Science and Technology of the Actinides and Beyond; Evans, W. J.,\u00a0Hanusa, T. P., Ed; Wiley: Chicester, 2019; 496 pages. Publications Origin of research: (U) = undergraduate; (G) = graduate; (P) = postdoctoral;&#8230;<\/p>\n","protected":false},"author":3769,"featured_media":0,"parent":0,"menu_order":4,"comment_status":"open","ping_status":"closed","template":"","meta":{"footnotes":""},"tags":[],"class_list":["post-6","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/my.vanderbilt.edu\/timothyhanusa\/wp-json\/wp\/v2\/pages\/6","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/my.vanderbilt.edu\/timothyhanusa\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/my.vanderbilt.edu\/timothyhanusa\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/my.vanderbilt.edu\/timothyhanusa\/wp-json\/wp\/v2\/users\/3769"}],"replies":[{"embeddable":true,"href":"https:\/\/my.vanderbilt.edu\/timothyhanusa\/wp-json\/wp\/v2\/comments?post=6"}],"version-history":[{"count":43,"href":"https:\/\/my.vanderbilt.edu\/timothyhanusa\/wp-json\/wp\/v2\/pages\/6\/revisions"}],"predecessor-version":[{"id":154,"href":"https:\/\/my.vanderbilt.edu\/timothyhanusa\/wp-json\/wp\/v2\/pages\/6\/revisions\/154"}],"wp:attachment":[{"href":"https:\/\/my.vanderbilt.edu\/timothyhanusa\/wp-json\/wp\/v2\/media?parent=6"}],"wp:term":[{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/my.vanderbilt.edu\/timothyhanusa\/wp-json\/wp\/v2\/tags?post=6"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}