Local ordering of polymer-tethered nanospheres and nanorods and the stabilization of the double gyroid phase

Posted by on Monday, October 31, 2011 in Recent Publications.

Citation:

Iacovella CR, Horsch MA, Glotzer SC (2008) Local ordering of polymer-tethered nanospheres and nanorods and the stabilization of the double gyroid phase, The Journal of Chemical Physics, 129, pp 044902

DOI:10.1063/1.2953581
arXiv:0806.0842v1

Abstract:

We present results of Brownian dynamics simulations of tethered nanospheres and tethered nanorods. Immiscibility between tether and nanoparticle facilitates microphase separation into the bicontinuous, double gyroid structure (first reported by Iacovella et al. [Phys. Rev. E 75, 040801(R) (2007) ] and Horsch et al. [J. Chem. Phys. 125, 184903 (2006)] , respectively). We demonstrate the ability of these nanoparticles to adopt distinct, minimal energy local packings, in which nanospheres form icosahedral-like clusters and nanorods form splayed hexagonal bundles. These local structures reduce packing frustration within the nodes of the double gyroid. We argue that the ability to locally order into stable structures is key to the formation of the double gyroid phase in these systems.

© 2008 American Institute of Physics

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