Schley Research Group

Publications

Categories

Work from our Group
Book Chapters and Perspectives
Collaborative Publications
Prior to Vanderbilt

Work from our Group

  1. Tandem Oligomerization-Hydrogenation Using Brønsted Acidic Iridium Hydride Catalysts

    2. Leitgeb, A. J.; Chapp, S. M.; Fast, C. D.; Fink, K. E.; Schley, N. D.
    Organometallics, 2025.
    DOI: 10.1021/acs.organomet.5c00160

    orlef7.2024.26.issue-29.largecover

  2. Bis(bicyclo[1.1.1]pentyl)chlorophosphine as a Precursor for the Preparation of Bis(bicyclo[1.1.1]pentyl)phosphines

    3. Perry, G. L.; Schley, N. D.
    Org. Lett., 2024, 26, 29, 6071-6075.
    DOI: 10.1021/acs.orglett.4c01190
    chlorophos

  3. Tris(bicyclo[1.1.1]pentyl)phosphine: An Exceptionally Small Tri-tert-alkylphosphine and Its Bis-Ligated Pd(0) Complex

    4. Perry, G. L.; Schley, N. D.
    J. Am. Chem. Soc., 2023, 145, 7005–7010.
    DOI: 10.1021/jacs.3c00885
    Highlighted: Org. Process Res. Dev. 2023, 27, 6, 993–1002. DOI: 10.1021/acs.oprd.3c00176
    bcp

  4. Light-Promoted Transfer of an Iridium Hydride in Alkyl Ether Cleavage

    5. Fast, C. D.; Schley, N. D.
    Organometallics, 2021, 40, 3291–3297.
    DOI: 10.1021/acs.organomet.1c00391
    photohydr

  5. Selective demethylation of O-aryl glycosides by iridium-catalyzed hydrosilylation

    6. Jones, C. A. H.; Schley, N. D.
    Chem. Commun., 2021, 57, 5953–5956.
    DOI: 10.1039/D1CC00496D
    carb_dem

  6. Reversible C(sp3)-Si Oxidative Addition of Unsupported Organosilanes: Effects of Silicon Substituents on Kinetics and Thermodynamics

    7. Chapp, S. M.; Schley, N. D.
    J. Am. Chem. Soc., 2021, 143, 5534–5539.
    DOI: 10.1021/jacs.1c01564
    silyl

  7. Ligand-Driven Advances in Iridium-Catalyzed sp3 C–H Borylation: 2,2′-Dipyridylarylmethane

    8. Jones, M. R.; Schley, N. D.
    Synlett, 2021, 32, 845-850.
    DOI: 10.1055/a-1344-1904
    synpac

  8. Product Inhibition in Nucleophilic Aromatic Substitution through DPPPent-Supported π-Arene Catalysis

    9. Mueller, B. R. J.; Schley, N. D.
    Dalton Transactions, 2020, 49, 10114–10119.
    DOI: 10.1039/D0DT00786B
    arene

  9. Selectivity and Mechanism of Iridium-Catalyzed Cyclohexyl Methyl Ether Cleavage

    10. Fast, C. D.; Jones, C. A. H.; Schley, N. D.
    ACS Catalysis, 2020, 10, 11, 6450–6456.
    DOI: 10.1021/acscatal.0c01718
    Featured at Organic-chemistry.org: Highlights: Reduction
    demeth

  10. Group-Transfer Reactions of a Cationic Iridium Alkoxycarbene Generated by Ether Dehydrogenation

    11. Chapp, S. M.; Schley, N. D.
    Inorg. Chem., 2020, 59, 10, 7143–7149.
    DOI: 10.1021/acs.inorgchem.0c00609
    grptransf

  11. Iridium-Catalyzed sp3 C–H Borylation in Hydrocarbon Solvent Enabled by 2,2′-Dipyridylarylmethane Ligands

    12. Jones, M. R.; Fast, C. D.; Schley, N. D.
    J. Am. Chem. Soc., 2020, 142, 14, 6488-6492.
    DOI: 10.1021/jacs.0c00524
    Featured at Organic-chemistry.org: Highlights: C-H functionalization
    jonesboryl

  12. Selective alkyl ether cleavage by cationic bis(phosphine)iridium complexes

    13. Jones, C. A. H.; Schley, N. D.
    Org. Biomol. Chem., 2019. 17, 1744-1748.
    DOI: 10.1039/C8OB02298D
    Invited submission – New Talent, 2019.
    debenzy

  13. Formation of a Delocalized Iridium Benzylidene with Azaquinone Methide Character via Alkoxycarbene Cleavage

    14. Zhang, Y.; Mueller, B. R. J.; Schley, N. D.
    Organometallics, 2018, 37 (12), pp 1825–1828.
    DOI: 10.1021/acs.organomet.8b00249
    azaqu

  14. Evidence for reversible cyclometalation in alkane dehydrogenation and C-O bond cleavage at iridium bis(phosphine) complexes

    15. Chapp, S. M.; Schley, N. D.
    Organometallics, 2017, 36 (22), pp 4355–4358.
    DOI: 10.1021/acs.organomet.7b00676
    irallyl

  15. Reversible alkoxycarbene formation by C–H activation of ethers via discrete, isolable intermediates

    16. Zhang, Y.; Schley, N. D.
    Chem. Commun., 2017, 53, 2130–2133.
    DOI: 10.1039/C6CC09838J
    dicarbene

    Book Chapters and Perspectives

  16. (1,5-Cyclooctadiene)bis(2-Me-allyl)ruthenium(II)

    17. Li, H.; Colacot, T. J; Schley, N. D.
    Encyclopedia of Reagents for Organic Synthesis, 2021.
    DOI: 10.1002/047084289X.rn01145.pub2

  17. Pioneers and Influencers in Organometallic Chemistry: Professor Robert Crabtree’s Storied Career via an Unusual Journey to the Ivy League

    18. Dobereiner, G. E.; Hazari, N.; Schley, N. D.
    Organometallics 2021, 40, 295–301.
    DOI: 10.1021/acs.organomet.0c00797

    Collaborative Work

  18. Unlocking Chromium Decarboxylative Ligand-to-Metal Charge Transfer: Efficient and Redox-Neutral Allylation of Aldehydes Using Carboxylic Acids

    19. Wu, S.†; Jiao, Z.†; Sung, A. T.; Faulhaber, A. B.; Schley, N. D.; Schuppe, A. W.
    J. Am. Chem. Soc. 2025, 147, 26, 22759–22767.
    DOI: 10.1021/jacs.5c04691

  19. Photocatalyzed Epimerization of Quaternary Stereocenters

    20. Wu, L.; McIntyre, B. N.; Wu, S.; Jiao, Z.; Fox, C. B.; Schley, N. D.; Schuppe, A. W.
    J. Am. Chem. Soc. 2025, 147, 13, 11080–11088.
    DOI: 10.1021/jacs.4c16769

  20. Total Synthesis and Pharmacological Evaluation of Phochrodines A–C

    21. Bouchard, J. L.; Chang, S.; Krishnan, S.; Presley, C. C.; Boutaud, O.; Schley, N. D.; Engers, D. W.; Engers, J. L.; Lindsley, C. W.; Bender, A. M.;
    J. Nat. Prod. 2025, 88, 4, 996–1003.
    DOI: 10.1021/acs.jnatprod.5c00104

  21. Synthesis, Structure, and Reactivity of Copper(I) Proazaphosphatrane Complexes

    22. Hoskins-Harris, J. E.; Kotera, K.; Hoilette, D. A., Jr.; Apostolou, W. E.; Osenga, V. A.; Thomas, J. I.; Schley, N. D.; Donald, K. J.; Johnson, M. W.
    Inorg. Chem. 2025, 64, 1132-1138.
    DOI: 10.1021/acs.inorgchem.4c04779

  22. Diastereoselective dearomative cycloaddition of bicyclobutanes with pyridinium ylides: a modular approach to multisubstituted azabicyclo[3.1.1]heptanes

    23. Dhake, K.; Woelk, K. J.; Krueckl, L. D. N.; Alberts, F.; Mutter, J.; Pohl, M. O.; Thomas, G. T.; Sharma, M.; Bjornerud-Brown, J.; Fernández, N. P.; Schley, N. D.; Leitch, D. C.
    Chem. Commun. 2024, 60, 13008-13011.
    DOI: 10.1039/D4CC04730C

  23. Mechanisms and Site Selectivity of (Het)Ar–X Oxidative Addition to Pd(0) Are Controlled by Frontier Molecular Orbital Symmetry

    24. Lu, J.; Schley, N. D.; Paci, I.; Leitch, D. C.
    Organometallics 2024, 43, 24, 3192–3203.
    DOI: 10.1021/acs.organomet.4c00224
    images_large_om4c00224_0013

  24. A Thermally Stable, Alkene-Free Palladium Source for Oxidative Addition Complex Formation and High-Turnover Catalysis

    25. Huang, J.; Ho, D. B.; Gaube, G.; Celuszak, H.; Becica, J.; Thomas, G. T.; Schley, N. D.; Leitch, D. C.
    Organometallics 2024, 43, 20, 2403–2412.
    DOI: 10.1021/acs.organomet.4c00125
    images_large_om4c00125_0009

  25. Alkene-Coordinated Palladium(0) Cross-Coupling Precatalysts: Comparing Oxidative Addition and Catalytic Reactivity for Dimethyl Fumarate and Maleic Anhydride Stabilizing Ligands

    26. Thomas, G. T.; Litman, J. Z.; Ho, D. B.; Huang, J.; Blonska, K.; Schley, N. D.; Leitch, D. C.
    Organometallics 2024, 43, 20, 2413–2426.
    DOI: 10.1021/acs.organomet.4c00065
    images_large_om4c00065_0017

  26. Five Hypotheses on the Origins of Temperature Dependence of 77Se NMR Shifts in Diselenides

    27. Koziel, A. C.; Bortoli, M.; Tremblay, M.; Zhao, Y.; Orian, L.; Yang, Z. J.; Schley, N. D.; Macdonald, J. E.,
    Inorg. Chem. 2024, 63, 12063-12072.
    DOI: 10.1021/acs.inorgchem.4c01025
    images_large_ic4c01025_0009

  27. Rapid sp3-Enriched Scaffold Generation via a Selective Aziridine Amide Ring-Opening Reaction

    28. Masahito, A.; Coleman, J. S.; Presley, C. C.; Schley, N. D.; Lindsley, C. W.
    J. Org. Chem. 2024, 89, 5, 3500-3508.
    DOI: 10.1021/acs.joc.3c02952
    images_large_jo3c02952_0008

  28. Comparative Analysis of the Donor Properties of Isomeric Pyrrolyl Phosphine Ligands

    29. Osenga, V. A.; Sykes, N. C.; Pa, S.; Bambha, M. K.; Schley, N. D.; Johnson, M. W.
    Organometallics 2024, 43, 14-20.
    DOI: 10.1021/acs.organomet.3c00467
    images_large_om3c00467_0014

  29. Enolate addition to bicyclobutanes enables expedient access to 2-oxo-bicyclohexane scaffolds

    30. Woelk, K. J.; Dhake, K.; Schley, N. D.; Leitch, D. C.
    Chem. Commun. 2023, 59, 13847-13850.
    DOI: 10.1039/D3CC04234K
    Get

  30. Vanol-Supported Lanthanide Complexes for Strong Circularly Polarized Luminescence at 1550 nm

    31. Adewuyi, J. A.; Schley, N. D.; Ung, G.
    Chem. Eur. J. 2023, 29, e202300800.
    DOI: 10.1002/chem.202300800
    chem202300800-toc-0001-m

  31. Synthesis, characterization and absolute configurations of methyl ladderanoates

    32. Harris, C. M.; Harris, T. M.; Stec, D. F.; Schley, N. D.; Johnson, J. L.; Covington, C. L.; Polavarapu, P. L.
    Chirality 2023, 35, 49-57.
    DOI: 10.1002/chir.23515
    chir23515-toc-0001-m

  32. Spinolate Lanthanide Complexes for High Circularly Polarized Luminescence Metrics in the Visible and Near-Infrared

    33. Willis, B.-A. N.; Schnable, D.; Schley, N. D.; Ung, G.
    J. Am. Chem. Soc. 2022, 144, 22421-22425.
    DOI: 10.1021/jacs.2c10364
    images_large_ja2c10364_0006

  33. Reassessment of N2 activation by low-valent Ti-amide complexes: a remarkable side-on bridged bis-N2 adduct is actually an arene adduct

    34. Huh, D. N.; Koby, R, F.; Stuart, Z. E.; Dunscomb, R. J.; Schley, N. D.; Tonks, I. A.
    Chem. Sci. 2022, 13, 13330-13337.
    DOI: 10.1039/D2SC04368H
    7c16e5f17bae5f9741ee6cc10dd05d32c70ec043

  34. Structure–Activity Relationships for the N-Me- Versus N-H-Amide Modification to Macrocyclic ent-Verticilide Antiarrhythmics

    35. Smith, A. N.; Thorpe, M. P.; Blackwell, D. J.; Batiste, S. M.; Hopkins, C. R.; Schley, N. D.; Knollmann, B. C.; Johnston, J. N.
    ACS Med. Chem. Lett. 2022, 13, 1755-1762.
    DOI: 10.1021/acsmedchemlett.2c00377
    images_large_ml2c00377_0011

  35. Circularly Polarized Luminescence from Uranyl Improves Resolution of Electronic Transitions

    36. Schnable, D.; Schley, N. D.; Ung, G.
    J. Am. Chem. Soc. 2022, 144, 10718-10722.
    DOI: 10.1021/jacs.2c03791
    images_large_ja2c03791_0006

  36. Strong Circularly Polarized Luminescence at 1550 nm from Enantiopure Molecular Erbium Complexes

    37. Mukthar, N. F. M.; Schley, N. D.; Ung, G.
    J. Am. Chem. Soc. 2022, 144, 6148-6153.
    DOI: 10.1021/jacs.2c01134
    images_large_ja2c01134_0007

  37. Synthesis of bright water-soluble circularly polarized luminescence emitters as potential sensors

    38. Adewuyi, J. A.; Schley, N. D.; Ung, G.
    Inorganic Chemistry Frontiers 2022, 9, 1474-1480.
    DOI: 10.1039/D1QI01398J
    D1QI01398J

  38. Trace Oxygen Affects Osmium Redox Polymer Synthesis for Wired Enzymatic Biosensors

    39. Calhoun, M. C.; Stachurski, C. D.; Winn, S. L.; Gizzie, E.; Daniel, A. W.; Schley, N. D.; Cliffel, D. E.
    J. Electrochem. Soc. 2022, 169, 016506.
    DOI: 10.1149/1945-7111/ac42a0

  39. Fluorine-induced diastereodivergence discovered in an equally rare enantioselective syn-aza-Henry reaction

    40. Bing, J. A.; Schley, N. D.; Johnston, J. N.
    Chemical Science 2022, 13, 2614-2623.
    DOI: 10.1039/D1SC05910F
    fdfcbb564a8f93bf18cd3122cbb6d125f04478c3

  40. Substituent Effect on the Circularly Polarized Luminescence of C1-Symmetric Carbene-Copper(I) Complexes

    41. Braker, E. E.; Mukthar, N. F. M.; Schley, N. D.; Ung, G.
    ChemPhotoChem 2021, 5, 902-905.
    DOI: 10.1002/cptc.202100068
    cptc202100068-toc-0001-m

  41. Synthesis and Cytotoxic Evaluation of Arimetamycin A and Its Daunorubicin and Doxorubicin Hybrids

    42. Huseman, E. D.; Byl, J. A. W.; Chapp, S. M.; Schley, N. D.; Osheroff, N.; Townsend, S. D.
    ACS Central Science 2021, 7, 1327-1337.
    DOI: 10.1021/acscentsci.1c00040
    images_large_oc1c00040_0010

  42. Electronic structure analysis and reactivity of the bimetallic bis-titanocene vinylcarboxylate complex, [(Cp2Ti)2(O2C3TMS2)].

    43. Huh, D. N.; Maity, A.; Van Trieste, G. P.; Schley, N. D.; Powers, D. C.; Tonks, I. A.
    Polyhedron 2021, 207, 115368.
    DOI: 10.1016/j.poly.2021.115368
    1-s2.0-S0277538721003508-ga1

  43. Di(indenyl)beryllium

    44. Koby, R. F.; Schley, N. D.; Hanusa, T. P.
    Angew. Chem. Int. Ed. 2021, 60, 21174-21178.
    DOI: 10.1002/anie.202107980
    anie202107980-toc-0001-m

  44. Mechanochemical Formation, Solution Rearrangements, and Catalytic Behavior of a Polymorphic Ca/K Allyl Complex

    45. Koby, R. F.; Doerr, A. M.; Rightmire, N. R.; Schley, N. D.; Brennessel, W. W.; Long, B. K.; Hanusa, T. P.
    Chem. Eur. J. 2021, 27,8195-8202.
    DOI: 10.1002/chem.202100589
    chem202100589-toc-0001-m

  45. How important are the intermolecular hydrogen bonding interactions in methanol solvent for interpreting the chiroptical properties?

    46. Polavarapu, P. L.; Santoro, E.; Covington, C. L.; Johnson, J. L.; Puente, A. R.; Schley, N. D.; Kallingathodi, Z.; Prakasan, P. C.; Haleema, S.; Thomas, A. A.; Ibnusaud, I.
    Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2021, 247, 119094
    DOI: 10.1016/j.saa.2020.119094
    1-s2.0-S1386142520310738-ga1

  46. High circularly polarized luminescence brightness from analogues of Shibasaki’s lanthanide complexes.

    47. Deng, M.; Schley, N. D.; Ung, G.
    Chem. Commun. 2020, 56, 14813-14816
    DOI: 10.1039/D0CC06568D
    shibisaki

  47. Alkali-metal- and halide-free dinuclear mixed-valent samarium and europium complexes.

    48. Mukthar, N. F. M.; Schley, N. D.; Ung, G.
    Dalton Transactions 2020, 49, 16059-16061
    DOI: 10.1039/D0DT01095B
    europ

  48. Systematic evaluation of the electronic effect of aluminum-containing ligands in iridium–aluminum and rhodium–aluminum bimetallic complexes

    49. Charles, R. M.; Taylor, N. S.; Mercado, A. A.; Frost, C. E.; Yokley, T. W.; Eckenhoff, W. T.; Schley, N. D.; DeYonker, N. J.; Brewster, T. P.
    Dalton Transactions 2020, 49, 13029-13043
    DOI: 10.1039/D0DT02472D
    bimet

  49. CO2 Capture by 2-(Methylamino)pyridine Ligated Aluminum Alkyl Complexes.

    50. Yokley, T. W.; Tupkar, H.; Schley, N. D.; DeYonker, N. J.; Brewster, T. P.
    Eur. J. Inorg. Chem. 2020, 2020, 2958-2967.
    DOI: 10.1002/ejic.202000437
    alum

  50. Study and modular synthesis of unsymmetrical bis(phosphino)pyrrole ligands.

    51. Fokwa, H. D.; Vidlak, J. F.; Weinberg, S. C.; Duplessis, I. D.; Schley, N. D.; Johnson, M. W.
    Dalton Transactions 2020, 49, 9957-9960.
    DOI: 10.1039/D0DT02063J
    pyrolyl

  51. Circularly Polarized Luminescence from Enantiopure C2-Symmetrical Tetrakis(2-pyridylmethyl)-1,2-diaminocyclohexane Lanthanide Complexes.

    52. Ayers, K. M.; Schley, N. D.; Ung, G.
    Inorg. Chem. 2020, 59, 11, 7657–7665.
    DOI: 10.1021/acs.inorgchem.0c00628
    images_large_ic0c00628_0010

  52. Synthesis of Enantiopure Lanthanide Complexes Supported by Hexadentate N,N′-Bis(methylbipyridyl)bipyrrolidine and Their Circularly Polarized Luminescence.

    53. Schnable, D.; Freedman, K.; Ayers, K. M.; Schley, N. D.; Kol, M.; Ung, G.
    Inorg. Chem. 2020, 59, 8498-8504.
    DOI: 10.1021/acs.inorgchem.0c00946
    images_large_ic0c00946_0005

  53. Algal Toxin Goniodomin A Binds Potassium Ion Selectively Yielding a Conformationally Altered Complex Having Biological Consequences.

    54. Tainter, C. J.; Schley, N. D.; Harris, C. M.; Stec, D. F.; Song, A. K.; Balinski, A.; May, J. C.; McLean, J. A.; Reece, K. S.; Harris, T. M.,
    Journal of Natural Products, 2020, 83, 4, 1069–1081.
    DOI: 10.1021/acs.jnatprod.9b01094
    images_large_np9b01094_0008

  54. Synthesis and Electronic Characterization of Iridium-Aluminum and Rhodium-Aluminum Heterobimetallic Complexes Bridged by 3-Oxypyridine and 4-Oxypyridine.

    55. Charles III, R. M.; Tupkar, H.; Helland, S. D.; Mercado, A. A.; Eckenhoff, W. T.; Schley, N. D.; DeYonker, N. J.; Brewster, T. P.
    Eur. J. Inorg. Chem. 2020, 2020, 1192-1198.
    DOI: 10.1002/ejic.201901317
    ejic201901317-toc-0001-m

  55. An η3-Bound Allyl Ligand on Magnesium in a Mechanochemically Generated Mg/K Allyl Complex.

    56. Koby, R. F.; Doerr, A. M.; Rightmire, N. R.; Schley, N. D.; Long, B. K.; Hanusa, T. P.
    Angew. Chem. Int. Ed. 2020, 59, 9542-9548.
    DOI: 10.1002/anie.201916410
    anie201916410-toc-0001-m

  56. Rhodium and iridium NNO-Scorpionate complexes: synthesis, structure, and reactivity with aluminum alkyls.

    57. Yokley, T. W.; Schley, N. D.; Brewster, T. P.
    Inorg. Chim. Acta 2020, 506, 119529.
    DOI: 10.1016/j.ica.2020.119529
    1-s2.0-S0020169319315178-ga1

  57. Yellow Circularly Polarized Luminescence from C1‐Symmetrical Copper(I) Complexes

    58. Deng, M.; Mukthar, N. F. M.; Schley, N. D.; Ung, G.
    Angew. Chem. Int. Ed., 2020, 59,1228–1231.
    DOI: 10.1002/anie.201913672
    anie201913672-toc-0001-m

  58. Catalytic, Enantioselective Synthesis of Cyclic Carbamates from Dialkyl Amines by CO2-Capture: Discovery, Development, and Mechanism

    59. Yousefi, R.; Struble, T. J.; Payne, J. L.; Vishe, M.; Schley, N. D.; Johnston, J. N.
    J. Am. Chem. Soc., 2019, 141 (1), 618-625.
    DOI: 10.1021/jacs.8b11793
    images_large_ja-2018-117937_0011

  59. Halide metathesis in overdrive: mechanochemical synthesis of a heterometallic group 1 allyl complex

    60. Koby, R. F.; Rightmire, N. R.; Schley, N. D.; Hanusa, T. P.; Brennessel, W. W.
    Beilstein Journal of Organic Chemistry 2019, 15, 1856-1863.
    DOI: 10.3762/bjoc.15.181

  60. Monometallic lanthanide salicylhydrazone complexes exhibiting strong near-infrared luminescence

    61. Ayers, K. M.; Schley, N. D.; Ung, G.
    Chem. Commun., 2019, 55, 8446–8449.
    DOI: 10.1039/C9CC03934A
    salicyl

  61. Hydrogen Activation and Hydrogenolysis Facilitated By Late-Transition-Metal–Aluminum Heterobimetallic Complexes.

    62. Charles, R. M.; Yokley, T. W.; Schley, N. D.; DeYonker, N. J.; Brewster, T. P.
    Inorganic Chemistry, 2019, 58, 12635-12645.
    DOI: 10.1021/acs.inorgchem.9b01359
    images_large_ic9b01359_0011

  62. Synthesis and characterization of rhodium–aluminum heterobimetallic complexes tethered by a 1,3-bis(diphenylphosphino)-2-propanoxy group.

    63. Li, Z.; Yokley, T. W.; Tran, S. L.; Zong, J.; Schley, N. D.; Brewster, T. P.
    Dalton Transactions, 2019, 48, 8782-8790.
    DOI: 10.1039/C9DT00938H
    tetheredpropanoxy

  63. Solid State Structures, Solution Behavior, and Luminescence of Simple Tetrakis(2-pyridylmethyl)ethylenediamine Lanthanide Complexes.

    64. Ayers, K. M.; Schley, N. D.; Ung, G.
    European Journal of Inorganic Chemistry, 2019, 2019, 3769-3775.
    DOI: 10.1002/ejic.201900609
    ejic201900609-toc-0001-m

  64. Absolute Configurations of Naturally Occurring [5]-and [3]-Ladderanoic Acids: Isolation, Chiroptical Spectroscopy and Crystallography

    65. Raghavan, V.; Johnson, J. L.; Stec, D. F.; Song, B.; Zajac, G.; Baranska, M.; Harris, C. M.; Schley, N. D.; Polavarapu, P. L.; Harris, T. M.
    Journal of Natural Products, 2018, 81 (12), 2654–2666.
    DOI: 10.1021/acs.jnatprod.8b00458.
    images_large_np-2018-00458e_0015

  65. Solvent Dependent Sensitization of Ytterbium and Neodymium via an Intramolecular Excimer

    66. Deng, M.; Schley, N. D.; Ung, G.
    Inorg. Chem. 2018, 57 (24), pp 15399–15405.
    DOI: 10.1021/acs.inorgchem.8b02709
    images_large_ic-2018-02709a_0011

  66. Mechanochemically driven transformations in organotin chemistry: stereochemical rearrangement, redox behavior, and dispersion-stabilized complexes

    67. Koby, F. R.; Hanusa, T. P.*; Schley, N. D.
    J. Am. Chem. Soc., 2018, 140 (46), pp 15934–15942.
    DOI: 10.1021/jacs.8b09862
    images_large_ja-2018-098623_0013

  67. Synthesis, Structure, and Reactivity of Palladium Proazaphosphatrane Complexes Invoked in C–N Cross-Coupling.

    68. Matthews, A. D.; Gravalis, G. M.; Schley, N. D.; Johnson, M. W.
    Organometallics 2018, 37 (18), pp 3073–3078.
    DOI: 10.1021/acs.organomet.8b00453
    images_large_om-2018-00453u_0011

  68. Synthesis and Characterization of Heterobimetallic Iridium–Aluminum and Rhodium–Aluminum Complexes

    69. Brewster, T. P.; Nguyen, T. H.; Li, Z.; Eckenhoff, W. T.; Schley, N. D.; DeYonker, N. J.
    Inorg. Chem. 2018, 57 (3), pp 1148–1157.
    DOI: 10.1021/acs.inorgchem.7b02601
    images_large_ic-2017-02601k_0014

    Prior to Vanderbilt

  69. Nickel-Catalyzed Negishi Arylations of Propargylic Bromides: A Mechanistic Investigation.

    70. Schley, N. D.; Fu, Gregory C.
    J. Am. Chem. Soc., 2014, 136 (47), 16588–16593.
    DOI: 10.1021/ja508718m

  70. Hydrogen-Transfer Catalysis with Cp*Ir-III Complexes: The Influence of the Ancillary Ligands.

    71. Hintermair, U.; Campos, J.; Brewster, T. P.; Pratt, L. M.; Schley, N. D.; Crabtree, R. H.
    ACS Catalysis 2014, 4, 99–108.
    DOI: 10.1021/cs400834q

  71. Domain Structure for an Amorphous Iridium-Oxide Water-Oxidation Catalyst Characterized by X-Ray Pair Distribution Function Analysis.

    72. Huang, J.; Blakemore, J. D.; Fazi, D.; Kokhan, O.; Schley, N. D.; Crabtree, R. H.; Brudvig, G. W.; Tiede, D. M.
    Phys. Chem. Chem. Phys. 2014, 16, 1814–1819.
    DOI: 10.1039/C3CP54878C

  72. Characterization of an Amorphous Iridium Water-Oxidation Catalyst Electrodeposited from Organometallic Precursors.

    73. Blakemore, J. D.; Mara, M. W.; Kushner-Lenhoff, M. N.; Schley, N. D.; Konezny, S. J.; Rivalta, I.; Negre, C. F. A.; Snoeberger, R. C.; Kokhan, O.; Huang, J.; Stickrath, A.; Tran, L. A.; Parr, M. L.; Chen, L. X.; Tiede, D. M.; Batista, V. S.; Crabtree, R. H.; Brudvig, G. W.
    Inorg. Chem. 2013, 52, 1860–1871.
    DOI: 10.1021/ic301968j

  73. Effects of Aqueous Buffers on Electrocatalytic Water Oxidation with an Iridium Oxide Material Electrodeposited in Thin Layers from an Organometallic Precursor.

    74. Kushner-Lenhoff, M. N.; Blakemore, J. D.; Schley, N. D.; Crabtree, R. H.; Brudvig, G. W.
    Dalton Trans. 2013, 42, 3617–3622.
    DOI: 10.1039/C2DT32326E

  74. Symmetrical Hydrogen Bonds in Iridium(III) Alkoxides with Relevance to Outer Sphere Hydrogen Transfer.

    75. Schley, N. D.; Halbert, S.; Raynaud, C.; Eisenstein, O.; Crabtree, R. H.
    Inorg. Chem. 2012, 51 (22), 12313–13323.
    DOI: 10.1021/ic301601c

  75. Mild, Reversible Reaction of Iridium(III) Amido Complexes with Carbon Dioxide.

    76. Dobereiner, G. E.; Wu, J.; Manas, M. G.; Schley, N. D.; Takase, M. K.; Crabtree, R. H.; Hazari, N.; Maseras, F.; Nova, A.
    Inorg. Chem. 2012, 51 (18), 9683–9693.
    DOI: 10.1021/ic300923c

  76. A Comparison of Amorphous Iridium Water-Oxidation Electrocatalysts Prepared from Soluble Precursors.

    77. Blakemore, J. D.; Schley, N. D.; Kushner-Lenhoff, M. N.; Winter, A. M.; D’Souza, F.; Crabtree, R. H.; Brudvig, G. W.
    Inorg. Chem. 2012, 51 (14), 7749–7763.
    DOI: 10.1021/ic300764f

  77. Ultrafast Photodriven Intramolecular Electron Transfer from an Iridium-Based Water-Oxidation Catalyst to Perylene Diimide Derivatives.

    78. Vagnini, M. T.; Smeigh, A. L.; Blakemore, J. D.; Eaton, S. W.; Schley, N. D.; D’Souza, F.; Crabtree, R. H.; Brudvig, G. W.; Co, D. T.; Wasielewski, M. R.
    Proc. Natl. Acad. Sci. U.S.A. 2012, 109 (39), 15651–15656.
    DOI: 10.1073/pnas.1202075109

  78. Characterization of an Activated Iridium Water Splitting Catalyst Using Infrared Photodissociation of H2 Tagged Ions.

    79. Garand, E.; Fournier, J. A.; Kamrath, M. Z.; Schley, N. D.; Crabtree, R. H.; Johnson, M. A.
    Phys. Chem. Chem. Phys. 2012, 14, 10109–10113.
    DOI: 10.1039/C2CP41490B

  79. Electron-Rich CpIr(biphenyl-2,2′-diyl) Complexes with π-Accepting Carbon Donor Ligands.

    80. Graeupner, J.; Brewster, T. P.; Blakemore, J. D.; Schley, N. D.; Thomsen, J. M.; Brudvig, G. W.; Hazari, N.; Crabtree, R. H.
    Organometallics 2012, 31, 7158–7164.
    DOI: 10.1021/om300696t

  80. Axially Chiral Dimeric Ir and Rh Complexes Bridged by Flexible NHC Ligands.

    81. Ashley, J. M.; Farnaby, J. H.; Hazari, N.*; Kim, K. E.; Luzik Jr, E. D.; Meehan, R, E.; Meyer, E. B.; Schley, N. D.; Schmeier T. J.; Tailor, A. N.
    Inorg. Chim. Acta. 2012, 380, 399–410.
    DOI: 10.1016/j.ica.2011.11.034

  81. Oxidative Synthesis of Amides and Pyrroles via Dehydrogenative Alcohol Oxidation by Ruthenium Diphosphine Diamine Complexes.

    82. Schley, N. D.; Dobereiner, G. E.; Crabtree, R. H.
    Organometallics 2011, 30 (15), 4174–4179.
    DOI: 10.1021/om2004755

  82. Distinguishing Homogeneous from Heterogeneous Catalysis in Electrode-Driven Water Oxidation with Molecular Iridium Complexes.

    83. Schley, N. D.; Blakemore, J. D.; Subbaiyan, N. K.; Incarvito, C. D.; D’Souza, F.; Crabtree, R. H.; Brudvig, G. W.
    J. Am. Chem. Soc. 2011, 133 (27), 10473–10481.
    DOI: 10.1021/ja2004522
    Highlighted: Meyer, T. J., Nat. Chem. 2011, 3, 757–758. DOI: 10.1038/nchem.1161

  83. Thiocyanate Linkage Isomerism in a Ruthenium Polypyridyl Complex.

    84. Brewster, T. P.; Ding, W.; Schley, N. D.; Hazari, N.; Batista, V. S.; Crabtree, R. H.
    Inorg. Chem. 2011, 50, 11938−11946.
    DOI: 10.1021/ic200950e

  84. Iridium-Catalyzed Hydrogenation of N-Heterocyclic Compounds under Mild Conditions by an Outer Sphere Pathway.

    85. Dobereiner, G. E.; Nova, A.; Schley, N. D.; Hazari, N.; Miller, S. J.; Eisenstein, O.; Crabtree, R. H.
    J. Am. Chem. Soc. 2011, 133 (19), 7547–7562.
    DOI: 10.1021/ja2014983

  85. An Iridium(IV) Species, [Cp*Ir(NHC)Cl]+, Related to a Water-Oxidation Catalyst.

    86. Brewster, T. P.; Blakemore, J. D.; Schley, N. D.; Incarvito, C. D.; Hazari, N.; Brudvig, G. W.; Crabtree, R. H.
    Organometallics 2011, 30 (5), 965–973.
    DOI: 10.1021/om101016s

  86. An Experimental-Theoretical Study of the Factors That Affect the Switch between Ruthenium-Catalyzed Dehydrogenative Amide Formation versus Amine Alkylation.

    87. Nova, A.; Balcells, D.; Schley, N. D.; Dobereiner, G. E.; Crabtree, R. H.; Eisenstein, O.
    Organometallics 2010, 29 (23), 6548–6558.
    DOI: 10.1021/om101015u

  87. Anodic Deposition of a Robust Iridium-Based Water-Oxidation Catalyst from Organometallic Precursors.

    88. Blakemore, J. D.; Schley, N. D.; Olack, G. W.; Incarvito, C. D.; Brudvig, G. W.; Crabtree, R. H.
    Chem. Sci. 2011, 2 (1), 94–98.
    DOI: 10.1039/C0SC00418A

  88. Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis.

    89. Blakemore, J. D.; Schley, N. D.; Balcells, D.; Hull, J. F.; Olack, G. W.; Incarvito, C. D.; Eisenstein, O.; Brudvig, G. W.; Crabtree, R. H.
    J. Am. Chem. Soc. 2010, 132 (45), 16017–16029.
    DOI: 10.1021/ja104775j

  89. Cp* Iridium Complexes Give Catalytic Alkane Hydroxylation with Retention of Stereochemistry.

    90. Zhou, M.; Schley, N. D.; Crabtree, R. H.
    J. Am. Chem. Soc. 2010, 132 (36), 12550–12551.
    DOI: 10.1021/ja1058247

  90. Acyl Protection Strategy for Synthesis of a Protic NHC Complex via N-Acyl Methanolysis.

    91. Dobereiner, G. E.; Chamberlin, C. A.; Schley, N. D.; Crabtree, R. H.
    Organometallics 2010, 29 (21), 5728–5731.
    DOI: 10.1021/om100452g

  91. Iridium and Ruthenium Complexes with Chelating N-Heterocyclic Carbenes: Efficient Catalysts for Transfer Hydrogenation, beta-Alkylation of Alcohols, and N-Alkylation of Amines.

    92. Gnanamgari, D.; Sauer, E. L. O.; Schley, N. D.; Butler, C.; Incarvito, C. D.; Crabtree, R. H.
    Organometallics 2009, 28 (1), 321–325.
    DOI: 10.1021/om800821q

  92. Alcohol Cross-Coupling Reactions Catalyzed by Ru and Ir Terpyridine Complexes.

    93. Gnanamgari, D.; Leung, C. H.; Schley, N. D.; Hilton, S. T.; Crabtree, R. H.
    Org. Biomol. Chem. 2008, 6 (23), 4442–4445.
    DOI: 10.1039/B815547J

  93. Isomeric Forms of Heavier Main Group Hydrides: Experimental and Theoretical Studies of the [Sn(Ar)H]2 (Ar=terphenyl) System.

    94. Rivard, E.; Fischer, R. C.; Wolf, R.; Peng, Y.; Merrill, W. A.; Schley, N. D.; Zhu, Z. L.; Pu, L.; Fettinger, J. C.; Teat, S. J.; Nowik, I.; Herber, R. H.; Takagi, N.; Nagase, S.; Power, P. P.
    J. Am. Chem. Soc. 2007, 129 (51), 16197–16208.
    DOI: 10.1021/ja076453m